Gold(III) Olefin Complexes

Nicky Savjani; Dragoş-Adrian Roşca; Mark Schormann; Manfred Bochmann

doi:10.1002/anie.201208356

Gold(III) Olefin Complexes

Nicky Savjani, Dragoş-Adrian Roşca, Mark Schormann, Manfred Bochmann

National Graphene Institute L5

Research output: Contribution to journal › Article › peer-review

Abstract

Zeise's salt gets company: 185 years after the report of the well-known platinum(II) ethylene compound, examples of isolable olefin complexes of its isoelectronic neighbor in the periodic table, gold(III), have been prepared (see picture). The complexes are very susceptible towards nucleophilic attack; there is also structural evidence for Au^III–Ag interactions.

Original language	English
Pages (from-to)	874-877
Number of pages	4
Journal	Angewandte Chemie International Edition
Volume	52
Issue number	3
Early online date	23 Nov 2012
DOIs	https://doi.org/10.1002/anie.201208356
Publication status	Published - 14 Jan 2013

Keywords

aurophilic bonds
coordination chemistry
ethylene
gold
homogeneous catalysis

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title = "Gold(III) Olefin Complexes",

abstract = "Zeise's salt gets company: 185 years after the report of the well-known platinum(II) ethylene compound, examples of isolable olefin complexes of its isoelectronic neighbor in the periodic table, gold(III), have been prepared (see picture). The complexes are very susceptible towards nucleophilic attack; there is also structural evidence for AuIII–Ag interactions.",

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AU - Savjani, Nicky

AU - Roşca, Dragoş-Adrian

AU - Schormann, Mark

AU - Bochmann, Manfred

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AB - Zeise's salt gets company: 185 years after the report of the well-known platinum(II) ethylene compound, examples of isolable olefin complexes of its isoelectronic neighbor in the periodic table, gold(III), have been prepared (see picture). The complexes are very susceptible towards nucleophilic attack; there is also structural evidence for AuIII–Ag interactions.

KW - aurophilic bonds

KW - coordination chemistry

KW - ethylene

KW - gold

KW - homogeneous catalysis

U2 - 10.1002/anie.201208356

DO - 10.1002/anie.201208356

M3 - Article

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JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

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Gold(III) Olefin Complexes

Abstract

Keywords

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