Heterometallic rings made from chromium stick together easily

Grigore A. Timco; Eric J L McInnes; Robin G. Pritchard; Floriana Tuna; Richard E P Winpenny

doi:10.1002/anie.200803637

Heterometallic rings made from chromium stick together easily

Grigore A. Timco, Eric J L McInnes, Robin G. Pritchard, Floriana Tuna, Richard E P Winpenny

Research output: Contribution to journal › Article › peer-review

Abstract

Sugared donuts: Reactions of hydrated chromium fluoride with N-ethyl-D-glucamine (H5Etglu) in pivalic acid, in the presence of nickel carbonate, leads to heterometallic "glu-ed" rings. These rings allow for construction of polyring arrays, for example an assembly where four glued rings are attached to tetrapyridylporphyrin (see structure; F yellow, O red, N blue, Cr purple, Ni green, C black). (Figure Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

Original language	English
Pages (from-to)	9681-9684
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	50
DOIs	https://doi.org/10.1002/anie.200803637
Publication status	Published - 1 Dec 2008

Keywords

Chromium
EPR spectroscopy
Heterometallic complexes
Molecular magnetism
Supramolecular chemistry

Access to Document

10.1002/anie.200803637

http://www3.interscience.wiley.com/cgi-bin/fulltext/121502997/PDFSTART

CCDC 696012: Experimental Crystal Structure Determination
Timco, G. (Contributor), Mcinnes, E. (Contributor), Pritchard, R. (Contributor), Tuna, F. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2009
DOI: 10.5517/ccrc80c, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccrc80c&sid=DataCite
Dataset
CCDC 696017: Experimental Crystal Structure Determination
Timco, G. (Contributor), Mcinnes, E. (Contributor), Pritchard, R. (Contributor), Tuna, F. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2009
DOI: 10.5517/ccrc85j, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccrc85j&sid=DataCite
Dataset
CCDC 696015: Experimental Crystal Structure Determination
Timco, G. (Contributor), Mcinnes, E. (Contributor), Pritchard, R. (Contributor), Tuna, F. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2009
DOI: 10.5517/ccrc83g, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccrc83g&sid=DataCite
Dataset

Cite this

@article{5762300d08674f45aac9a9896a8553a0,

title = "Heterometallic rings made from chromium stick together easily",

abstract = "Sugared donuts: Reactions of hydrated chromium fluoride with N-ethyl-D-glucamine (H5Etglu) in pivalic acid, in the presence of nickel carbonate, leads to heterometallic {"}glu-ed{"} rings. These rings allow for construction of polyring arrays, for example an assembly where four glued rings are attached to tetrapyridylporphyrin (see structure; F yellow, O red, N blue, Cr purple, Ni green, C black). (Figure Presented). {\textcopyright} 2008 Wiley-VCH Verlag GmbH & Co. KGaA.",

keywords = "Chromium, EPR spectroscopy, Heterometallic complexes, Molecular magnetism, Supramolecular chemistry",

author = "Timco, {Grigore A.} and McInnes, {Eric J L} and Pritchard, {Robin G.} and Floriana Tuna and Winpenny, {Richard E P}",

year = "2008",

month = dec,

day = "1",

doi = "10.1002/anie.200803637",

language = "English",

volume = "47",

pages = "9681--9684",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley & Sons Ltd",

number = "50",

}

TY - JOUR

T1 - Heterometallic rings made from chromium stick together easily

AU - Timco, Grigore A.

AU - McInnes, Eric J L

AU - Pritchard, Robin G.

AU - Tuna, Floriana

AU - Winpenny, Richard E P

PY - 2008/12/1

Y1 - 2008/12/1

N2 - Sugared donuts: Reactions of hydrated chromium fluoride with N-ethyl-D-glucamine (H5Etglu) in pivalic acid, in the presence of nickel carbonate, leads to heterometallic "glu-ed" rings. These rings allow for construction of polyring arrays, for example an assembly where four glued rings are attached to tetrapyridylporphyrin (see structure; F yellow, O red, N blue, Cr purple, Ni green, C black). (Figure Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

AB - Sugared donuts: Reactions of hydrated chromium fluoride with N-ethyl-D-glucamine (H5Etglu) in pivalic acid, in the presence of nickel carbonate, leads to heterometallic "glu-ed" rings. These rings allow for construction of polyring arrays, for example an assembly where four glued rings are attached to tetrapyridylporphyrin (see structure; F yellow, O red, N blue, Cr purple, Ni green, C black). (Figure Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

KW - Chromium

KW - EPR spectroscopy

KW - Heterometallic complexes

KW - Molecular magnetism

KW - Supramolecular chemistry

U2 - 10.1002/anie.200803637

DO - 10.1002/anie.200803637

M3 - Article

SN - 1433-7851

VL - 47

SP - 9681

EP - 9684

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 50

ER -

Heterometallic rings made from chromium stick together easily

Abstract

Keywords

Access to Document

Fingerprint

Datasets

CCDC 696012: Experimental Crystal Structure Determination

CCDC 696017: Experimental Crystal Structure Determination

CCDC 696015: Experimental Crystal Structure Determination

Cite this