High adsorption of ammonia in a titanium–based metal-organic framework

Xiangdi Zeng; Jiangnan Li; Meng He; Wanpeng Lu; Danielle Crawshaw; Lixia Guo; Yujie Ma; Meredydd Kippax-Jones; Yongqiang Cheng; Pascal Manuel; Svemir Rudic; Mark david Frogley; Martin Schroder; Sihai Yang

doi:10.1039/D4CC01449A

High adsorption of ammonia in a titanium–based metal-organic framework

Xiangdi Zeng, Jiangnan Li, Meng He, Wanpeng Lu, Danielle Crawshaw, Lixia Guo, Yujie Ma, Meredydd Kippax-Jones, Yongqiang Cheng, Pascal Manuel, Svemir Rudic, Mark david Frogley, Martin Schroder, Sihai Yang

Research output: Contribution to journal › Article › peer-review

Abstract

We report the high adsorption of NH3 in the titanium-based metal-organic framework, MFM-300(Ti), comprising extended [TiO₆]∞ chains linked by biphenyl-3,3’,5,5’-tetracarboxylate ligands. At 273 K and 1 bar, MFM-300(Ti) shows an exceptional NH3 uptake of 23.4 mmol g^–1 with a record-high packing density of 0.84 g cm^–3. Dynamic breakthrough experiments confirm the excellent uptake and separation of NH₃ at low concentration (1000 ppm). The combination of in situ neutron powder diffraction and spectroscopic studies reveal strong, yet reversible binding interactions of NH₃ to the framework oxygen sites.

Original language	English
Journal	Chemical Communications
Early online date	26 Apr 2024
DOIs	https://doi.org/10.1039/D4CC01449A
Publication status	E-pub ahead of print - 26 Apr 2024

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title = "High adsorption of ammonia in a titanium–based metal-organic framework",

abstract = "We report the high adsorption of NH3 in the titanium-based metal-organic framework, MFM-300(Ti), comprising extended [TiO6]∞ chains linked by biphenyl-3,3{\textquoteright},5,5{\textquoteright}-tetracarboxylate ligands. At 273 K and 1 bar, MFM-300(Ti) shows an exceptional NH3 uptake of 23.4 mmol g–1 with a record-high packing density of 0.84 g cm–3. Dynamic breakthrough experiments confirm the excellent uptake and separation of NH3 at low concentration (1000 ppm). The combination of in situ neutron powder diffraction and spectroscopic studies reveal strong, yet reversible binding interactions of NH3 to the framework oxygen sites.",

author = "Xiangdi Zeng and Jiangnan Li and Meng He and Wanpeng Lu and Danielle Crawshaw and Lixia Guo and Yujie Ma and Meredydd Kippax-Jones and Yongqiang Cheng and Pascal Manuel and Svemir Rudic and Frogley, {Mark david} and Martin Schroder and Sihai Yang",

year = "2024",

month = apr,

day = "26",

doi = "10.1039/D4CC01449A",

language = "English",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - High adsorption of ammonia in a titanium–based metal-organic framework

AU - Zeng, Xiangdi

AU - Li, Jiangnan

AU - He, Meng

AU - Lu, Wanpeng

AU - Crawshaw, Danielle

AU - Guo, Lixia

AU - Ma, Yujie

AU - Kippax-Jones, Meredydd

AU - Cheng, Yongqiang

AU - Manuel, Pascal

AU - Rudic, Svemir

AU - Frogley, Mark david

AU - Schroder, Martin

AU - Yang, Sihai

PY - 2024/4/26

Y1 - 2024/4/26

N2 - We report the high adsorption of NH3 in the titanium-based metal-organic framework, MFM-300(Ti), comprising extended [TiO6]∞ chains linked by biphenyl-3,3’,5,5’-tetracarboxylate ligands. At 273 K and 1 bar, MFM-300(Ti) shows an exceptional NH3 uptake of 23.4 mmol g–1 with a record-high packing density of 0.84 g cm–3. Dynamic breakthrough experiments confirm the excellent uptake and separation of NH3 at low concentration (1000 ppm). The combination of in situ neutron powder diffraction and spectroscopic studies reveal strong, yet reversible binding interactions of NH3 to the framework oxygen sites.

AB - We report the high adsorption of NH3 in the titanium-based metal-organic framework, MFM-300(Ti), comprising extended [TiO6]∞ chains linked by biphenyl-3,3’,5,5’-tetracarboxylate ligands. At 273 K and 1 bar, MFM-300(Ti) shows an exceptional NH3 uptake of 23.4 mmol g–1 with a record-high packing density of 0.84 g cm–3. Dynamic breakthrough experiments confirm the excellent uptake and separation of NH3 at low concentration (1000 ppm). The combination of in situ neutron powder diffraction and spectroscopic studies reveal strong, yet reversible binding interactions of NH3 to the framework oxygen sites.

U2 - 10.1039/D4CC01449A

DO - 10.1039/D4CC01449A

M3 - Article

SN - 1359-7345

JO - Chemical Communications

JF - Chemical Communications

ER -

High adsorption of ammonia in a titanium–based metal-organic framework

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