High ammonia adsorption in copper-carboxylate materials: host-guest interactions and crystalline-amorphous-crystalline phase transitions

Wanpeng Lu; Yinlin Chen; Zi Wang; Lixia   Guo; Jin Chen; Yujie Ma; Weiyao Li; Jiangnan Li; Meng He; Mengtian Fan; Alena M. Sheveleva; Floriana Tuna; Eric J. L. Mcinnes; Mark D. Frogley; Philip A. Chater; Catherine  Dejoie; Martin Schröder; Sihai Yang

doi:10.1039/D4CC02604G

High ammonia adsorption in copper-carboxylate materials: host-guest interactions and crystalline-amorphous-crystalline phase transitions

Wanpeng Lu
, Yinlin Chen
, Zi Wang
, Lixia Guo
, Jin Chen
, Yujie Ma
, Weiyao Li
, Jiangnan Li
, Meng He
, Mengtian Fan
, Alena M. Sheveleva
, Floriana Tuna
, Eric J. L. Mcinnes
, Mark D. Frogley
, Philip A. Chater
, Catherine Dejoie
, Martin Schröder
, Sihai Yang

Research output: Contribution to journal › Article › peer-review

Abstract

The development of materials for ammonia (NH3) storage is an important and challenging task. Here, we report the high NH3 uptake in a series of copper-carboxylate materials, namely MFM-100, MFM-101, MFM-102, MFM-126, MFM-127, MFM-190(F), MFM-170, and Cu-MOP-1a. At 273 K and 1 bar, MFM-101 shows an exceptional uptake of 21.9 mmol g−1. X-ray pair distribution function analysis reveals an unusual crystalline-amorphous-crystalline phase transition for the isoreticular MFM-100, MFM-101 and MFM-102 upon adsorption and desorption of NH3 followed by regeneration in water. In situ X-ray diffraction, synchrotron infrared micro-spectroscopy, and electron paramagnetic resonance spectroscopy are employed to elucidate the presence of strong Cu(II)⋯NH3 interactions and changes in coordination at the [Cu2(O2CR)4] (R = di-, tri-, and tetra-phenyl ligands) paddlewheel.

Original language	English
Pages (from-to)	12385-12388
Journal	Chem. Comm.
Volume	60
Issue number	85
DOIs	https://doi.org/10.1039/D4CC02604G
Publication status	Published - 16 Sept 2024

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10.1039/D4CC02604GLicence: CC BY

EPSRC National Research Facility for Electron Paramagnetic Resonance
Collison, D. (Academic lead), Mcinnes, E. (Academic lead), Tuna, F. (Academic lead), Bowen, A. (Academic lead), Shanmugam, M. (Senior Technical Specialist), Brookfield, A. (Technical Specialist), Fleming, E. (Other) & Cliff, M. (Core Facility Lead)
FSE Research
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Lu, W., Chen, Y., Wang, Z., Guo, L., Chen, J., Ma, Y., Li, W., Li, J., He, M., Fan, M., Sheveleva, A. M., Tuna, F., Mcinnes, E. J. L., Frogley, M. D., Chater, P. A., Dejoie, C., Schröder, M., & Yang, S. (2024). High ammonia adsorption in copper-carboxylate materials: host-guest interactions and crystalline-amorphous-crystalline phase transitions. Chem. Comm., 60(85), 12385-12388. https://doi.org/10.1039/D4CC02604G

@article{f095b5ab740747f08ee07db80cdbe4cb,

title = "High ammonia adsorption in copper-carboxylate materials: host-guest interactions and crystalline-amorphous-crystalline phase transitions",

abstract = "The development of materials for ammonia (NH3) storage is an important and challenging task. Here, we report the high NH3 uptake in a series of copper-carboxylate materials, namely MFM-100, MFM-101, MFM-102, MFM-126, MFM-127, MFM-190(F), MFM-170, and Cu-MOP-1a. At 273 K and 1 bar, MFM-101 shows an exceptional uptake of 21.9 mmol g−1. X-ray pair distribution function analysis reveals an unusual crystalline-amorphous-crystalline phase transition for the isoreticular MFM-100, MFM-101 and MFM-102 upon adsorption and desorption of NH3 followed by regeneration in water. In situ X-ray diffraction, synchrotron infrared micro-spectroscopy, and electron paramagnetic resonance spectroscopy are employed to elucidate the presence of strong Cu(II)⋯NH3 interactions and changes in coordination at the [Cu2(O2CR)4] (R = di-, tri-, and tetra-phenyl ligands) paddlewheel.",

author = "Wanpeng Lu and Yinlin Chen and Zi Wang and Lixia Guo and Jin Chen and Yujie Ma and Weiyao Li and Jiangnan Li and Meng He and Mengtian Fan and Sheveleva, \{Alena M.\} and Floriana Tuna and Mcinnes, \{Eric J. L.\} and Frogley, \{Mark D.\} and Chater, \{Philip A.\} and Catherine Dejoie and Martin Schr{\"o}der and Sihai Yang",

year = "2024",

month = sep,

day = "16",

doi = "10.1039/D4CC02604G",

language = "English",

volume = "60",

pages = "12385--12388",

journal = "Chem. Comm.",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "85",

}

Lu, W, Chen, Y, Wang, Z, Guo, L, Chen, J, Ma, Y, Li, W, Li, J, He, M, Fan, M, Sheveleva, AM, Tuna, F , Mcinnes, EJL, Frogley, MD, Chater, PA, Dejoie, C, Schröder, M & Yang, S 2024, 'High ammonia adsorption in copper-carboxylate materials: host-guest interactions and crystalline-amorphous-crystalline phase transitions', Chem. Comm., vol. 60, no. 85, pp. 12385-12388. https://doi.org/10.1039/D4CC02604G

TY - JOUR

T1 - High ammonia adsorption in copper-carboxylate materials: host-guest interactions and crystalline-amorphous-crystalline phase transitions

AU - Lu, Wanpeng

AU - Chen, Yinlin

AU - Wang, Zi

AU - Guo, Lixia

AU - Chen, Jin

AU - Ma, Yujie

AU - Li, Weiyao

AU - Li, Jiangnan

AU - He, Meng

AU - Fan, Mengtian

AU - Sheveleva, Alena M.

AU - Tuna, Floriana

AU - Mcinnes, Eric J. L.

AU - Frogley, Mark D.

AU - Chater, Philip A.

AU - Dejoie, Catherine

AU - Schröder, Martin

AU - Yang, Sihai

PY - 2024/9/16

Y1 - 2024/9/16

N2 - The development of materials for ammonia (NH3) storage is an important and challenging task. Here, we report the high NH3 uptake in a series of copper-carboxylate materials, namely MFM-100, MFM-101, MFM-102, MFM-126, MFM-127, MFM-190(F), MFM-170, and Cu-MOP-1a. At 273 K and 1 bar, MFM-101 shows an exceptional uptake of 21.9 mmol g−1. X-ray pair distribution function analysis reveals an unusual crystalline-amorphous-crystalline phase transition for the isoreticular MFM-100, MFM-101 and MFM-102 upon adsorption and desorption of NH3 followed by regeneration in water. In situ X-ray diffraction, synchrotron infrared micro-spectroscopy, and electron paramagnetic resonance spectroscopy are employed to elucidate the presence of strong Cu(II)⋯NH3 interactions and changes in coordination at the [Cu2(O2CR)4] (R = di-, tri-, and tetra-phenyl ligands) paddlewheel.

AB - The development of materials for ammonia (NH3) storage is an important and challenging task. Here, we report the high NH3 uptake in a series of copper-carboxylate materials, namely MFM-100, MFM-101, MFM-102, MFM-126, MFM-127, MFM-190(F), MFM-170, and Cu-MOP-1a. At 273 K and 1 bar, MFM-101 shows an exceptional uptake of 21.9 mmol g−1. X-ray pair distribution function analysis reveals an unusual crystalline-amorphous-crystalline phase transition for the isoreticular MFM-100, MFM-101 and MFM-102 upon adsorption and desorption of NH3 followed by regeneration in water. In situ X-ray diffraction, synchrotron infrared micro-spectroscopy, and electron paramagnetic resonance spectroscopy are employed to elucidate the presence of strong Cu(II)⋯NH3 interactions and changes in coordination at the [Cu2(O2CR)4] (R = di-, tri-, and tetra-phenyl ligands) paddlewheel.

U2 - 10.1039/D4CC02604G

DO - 10.1039/D4CC02604G

M3 - Article

SN - 1359-7345

VL - 60

SP - 12385

EP - 12388

JO - Chem. Comm.

JF - Chem. Comm.

IS - 85

ER -

High ammonia adsorption in copper-carboxylate materials: host-guest interactions and crystalline-amorphous-crystalline phase transitions

Abstract

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EPSRC National Research Facility for Electron Paramagnetic Resonance

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