Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence

A.S. Romanov; D. Di; L. Yang; J. Fernandez-Cestau; C.R. Becker; C.E. James; B. Zhu; M. Linnolahti; D. Credgington; M. Bochmann

doi:10.1039/c6cc02349e

Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence

A.S. Romanov, D. Di, L. Yang, J. Fernandez-Cestau, C.R. Becker, C.E. James, B. Zhu, M. Linnolahti, D. Credgington, M. Bochmann

Materials Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Linear two-coordinate copper complexes of cyclic (alkyl)(amino)carbenes (CAAC)CuX (X = halide) show photoluminescence with solid-state quantum yields of up to 96%; in contrast to previously reported Cu photoemitters the emission is independent of temperature over the range T = 4–300 K and occurs very efficiently by prompt rather than delayed fluorescence, with lifetimes in the sub-nanosecond range.

Original language	English
Journal	Chemical Communications
DOIs	https://doi.org/10.1039/c6cc02349e
Publication status	Published - 12 Apr 2016

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10.1039/c6cc02349eLicence: CC BY

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title = "Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence",

abstract = "Linear two-coordinate copper complexes of cyclic (alkyl)(amino)carbenes (CAAC)CuX (X = halide) show photoluminescence with solid-state quantum yields of up to 96%; in contrast to previously reported Cu photoemitters the emission is independent of temperature over the range T = 4–300 K and occurs very efficiently by prompt rather than delayed fluorescence, with lifetimes in the sub-nanosecond range.",

author = "A.S. Romanov and D. Di and L. Yang and J. Fernandez-Cestau and C.R. Becker and C.E. James and B. Zhu and M. Linnolahti and D. Credgington and M. Bochmann",

year = "2016",

month = apr,

day = "12",

doi = "10.1039/c6cc02349e",

language = "English",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence

AU - Romanov, A.S.

AU - Di, D.

AU - Yang, L.

AU - Fernandez-Cestau, J.

AU - Becker, C.R.

AU - James, C.E.

AU - Zhu, B.

AU - Linnolahti, M.

AU - Credgington, D.

AU - Bochmann, M.

PY - 2016/4/12

Y1 - 2016/4/12

N2 - Linear two-coordinate copper complexes of cyclic (alkyl)(amino)carbenes (CAAC)CuX (X = halide) show photoluminescence with solid-state quantum yields of up to 96%; in contrast to previously reported Cu photoemitters the emission is independent of temperature over the range T = 4–300 K and occurs very efficiently by prompt rather than delayed fluorescence, with lifetimes in the sub-nanosecond range.

AB - Linear two-coordinate copper complexes of cyclic (alkyl)(amino)carbenes (CAAC)CuX (X = halide) show photoluminescence with solid-state quantum yields of up to 96%; in contrast to previously reported Cu photoemitters the emission is independent of temperature over the range T = 4–300 K and occurs very efficiently by prompt rather than delayed fluorescence, with lifetimes in the sub-nanosecond range.

UR - http://www.scopus.com/inward/record.url?eid=2-s2.0-84966747096&partnerID=MN8TOARS

U2 - 10.1039/c6cc02349e

DO - 10.1039/c6cc02349e

M3 - Article

SN - 1359-7345

JO - Chemical Communications

JF - Chemical Communications

ER -

Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence

Abstract

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