Homopolymers and block copolymers of p-phenylenevinylene-2, 5-diethylhexyloxy-p-phenylenevinylene and m-phenylenevinylene-2, 5diethylhexyloxy-p-phenylenevinylene by ring-opening metathesis polymerization

Chin Yang Yu; Masaki Horie; Andrew M. Spring; Kim Tremei; Michael L. Turner

doi:10.1021/ma901966g

Homopolymers and block copolymers of p-phenylenevinylene-2, 5-diethylhexyloxy-p-phenylenevinylene and m-phenylenevinylene-2, 5diethylhexyloxy-p-phenylenevinylene by ring-opening metathesis polymerization

Chin Yang Yu, Masaki Horie, Andrew M. Spring, Kim Tremei, Michael L. Turner

Research output: Contribution to journal › Article › peer-review

Abstract

p-Phenylenevinylene-2, 5-diethylhexyloxy-p-phenylenevinylene and m-phenylenevinylene-2, 5-diethylhexyloxy-p-phenylenevinylene homopolymers (3 and 4) have been prepared by the ring-opening metathesis polymerization (ROMP) of strained cyclophanedienes, initiated by the second generation Grubbs catalyst. The as-formed polymers have a backbone of alternating cis- and trans-vinylene linkages due to the opening of only one vinylene of the cyclophanediene. Irradiation with UV light results in an isomerization to an all-trans-vinylene microstructure for all polymers. The polymer chain ends remain active after complete consumption of the cyclophanediene, and block copolymers can be prepared by addition of further cyclophanediene. The optical and electronic properties of the homopolymers and block copolymers are reported. © 2009 American Chemical Society.

Original language	English
Pages (from-to)	222-232
Number of pages	10
Journal	Macromolecules
Volume	43
Issue number	1
DOIs	https://doi.org/10.1021/ma901966g
Publication status	Published - 12 Jan 2010

Keywords

Polymers Role: PEP (Physical, engineering or chemical process), PRP (Properties), SPN (Synthetic preparation), PREP (Preparation), PROC (Process) (block, diblock
homopolymers and block copolymers of p-phenylenevinylene-2,5-diethylhexyloxy-p-phenylenevinylene and m-phenylenevinylene-2,5-diethylhexyloxy-p-phenylenevinylene by ring-opening metathesis polymn.)
Polymerization (block
Poly(arylenealkenylenes) Role: PEP (Physical, engineering or chemical process), PRP (Properties), SPN (Synthetic preparation), PREP (Preparation), PROC (Process) (block
Isomerization (cis-trans, photochem.
Band gap
Cyclic voltammetry
Glass transition temperature
HOMO
Heat capacity
LUMO
Luminescence
Molecular weight
Oxidation potential
Polydispersity
Polymer chains
Reduction potential
Thermal stability
UV and visible spectra
UV radiation (homopolymers and block copolymers of p-phenylenevinylene-2,5-diethylhexyloxy-p-phenylenevinylene and m-phenylenevinylene-2,5-diethylhexyloxy-p-phenylenevinylene by ring-opening metathesis polymn.)
Poly(arylenealkenylenes) Role: PEP (Physical, engineering or chemical process), PRP (Properties), RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), PROC (Process), RACT (Reactant or reagent) (homopolymers and block copolymers of p-phenyle
Polymerization (metathetic, ring-opening
Band gap (optical
Casting of polymeric materials (spin
cyclophanediene deriv ring opening metathesis polymn photoisomerization electrochem property

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@article{80a546ed68dc47cf89f4578d82901bb9,

title = "Homopolymers and block copolymers of p-phenylenevinylene-2, 5-diethylhexyloxy-p-phenylenevinylene and m-phenylenevinylene-2, 5diethylhexyloxy-p-phenylenevinylene by ring-opening metathesis polymerization",

abstract = "p-Phenylenevinylene-2, 5-diethylhexyloxy-p-phenylenevinylene and m-phenylenevinylene-2, 5-diethylhexyloxy-p-phenylenevinylene homopolymers (3 and 4) have been prepared by the ring-opening metathesis polymerization (ROMP) of strained cyclophanedienes, initiated by the second generation Grubbs catalyst. The as-formed polymers have a backbone of alternating cis- and trans-vinylene linkages due to the opening of only one vinylene of the cyclophanediene. Irradiation with UV light results in an isomerization to an all-trans-vinylene microstructure for all polymers. The polymer chain ends remain active after complete consumption of the cyclophanediene, and block copolymers can be prepared by addition of further cyclophanediene. The optical and electronic properties of the homopolymers and block copolymers are reported. {\textcopyright} 2009 American Chemical Society.",

keywords = "Polymers Role: PEP (Physical, engineering or chemical process), PRP (Properties), SPN (Synthetic preparation), PREP (Preparation), PROC (Process) (block, diblock, homopolymers and block copolymers of p-phenylenevinylene-2,5-diethylhexyloxy-p-phenylenevinylene and m-phenylenevinylene-2,5-diethylhexyloxy-p-phenylenevinylene by ring-opening metathesis polymn.), Polymerization (block, Poly(arylenealkenylenes) Role: PEP (Physical, engineering or chemical process), PRP (Properties), SPN (Synthetic preparation), PREP (Preparation), PROC (Process) (block, Isomerization (cis-trans, photochem., Band gap, Cyclic voltammetry, Glass transition temperature, HOMO, Heat capacity, LUMO, Luminescence, Molecular weight, Oxidation potential, Polydispersity, Polymer chains, Reduction potential, Thermal stability, UV and visible spectra, UV radiation (homopolymers and block copolymers of p-phenylenevinylene-2,5-diethylhexyloxy-p-phenylenevinylene and m-phenylenevinylene-2,5-diethylhexyloxy-p-phenylenevinylene by ring-opening metathesis polymn.), Poly(arylenealkenylenes) Role: PEP (Physical, engineering or chemical process), PRP (Properties), RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), PROC (Process), RACT (Reactant or reagent) (homopolymers and block copolymers of p-phenyle, Polymerization (metathetic, ring-opening, Band gap (optical, Casting of polymeric materials (spin, cyclophanediene deriv ring opening metathesis polymn photoisomerization electrochem property",

author = "Yu, {Chin Yang} and Masaki Horie and Spring, {Andrew M.} and Kim Tremei and Turner, {Michael L.}",

note = "CAN 152:75531 35-7 Chemistry of Synthetic High Polymers Organic Materials Innovation, Centre School of Chemistry,The University of Manchester,Manchester,UK. Journal 1201800-67-0P Role: PEP (Physical, engineering or chemical process), PRP (Properties), RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), PROC (Process), RACT (Reactant or reagent) (homopolymers and block copolymers of p-phenylenevinylene-2,5-diethylhexyloxy-p-phenylenevinylene and m-phenylenevinylene-2,5-diethylhexyloxy-p-phenylenevinylene by ring-opening metathesis polymn.); 1201800-69-2P; 1201800-70-5P Role: PEP (Physical, engineering or chemical process), PRP (Properties), SPN (Synthetic preparation), PREP (Preparation), PROC (Process) (homopolymers and block copolymers of p-phenylenevinylene-2,5-diethylhexyloxy-p-phenylenevinylene and m-phenylenevinylene-2,5-diethylhexyloxy-p-phenylenevinylene by ring-opening metathesis polymn.)",

year = "2010",

month = jan,

day = "12",

doi = "10.1021/ma901966g",

language = "English",

volume = "43",

pages = "222--232",

journal = "Macromolecules",

issn = "0024-9297",

publisher = "American Chemical Society",

number = "1",

}

Homopolymers and block copolymers of p-phenylenevinylene-2, 5-diethylhexyloxy-p-phenylenevinylene and m-phenylenevinylene-2, 5diethylhexyloxy-p-phenylenevinylene by ring-opening metathesis polymerization. / Yu, Chin Yang; Horie, Masaki; Spring, Andrew M. et al.
In: Macromolecules, Vol. 43, No. 1, 12.01.2010, p. 222-232.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Homopolymers and block copolymers of p-phenylenevinylene-2, 5-diethylhexyloxy-p-phenylenevinylene and m-phenylenevinylene-2, 5diethylhexyloxy-p-phenylenevinylene by ring-opening metathesis polymerization

AU - Yu, Chin Yang

AU - Horie, Masaki

AU - Spring, Andrew M.

AU - Tremei, Kim

AU - Turner, Michael L.

N1 - CAN 152:75531 35-7 Chemistry of Synthetic High Polymers Organic Materials Innovation, Centre School of Chemistry,The University of Manchester,Manchester,UK. Journal 1201800-67-0P Role: PEP (Physical, engineering or chemical process), PRP (Properties), RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), PROC (Process), RACT (Reactant or reagent) (homopolymers and block copolymers of p-phenylenevinylene-2,5-diethylhexyloxy-p-phenylenevinylene and m-phenylenevinylene-2,5-diethylhexyloxy-p-phenylenevinylene by ring-opening metathesis polymn.); 1201800-69-2P; 1201800-70-5P Role: PEP (Physical, engineering or chemical process), PRP (Properties), SPN (Synthetic preparation), PREP (Preparation), PROC (Process) (homopolymers and block copolymers of p-phenylenevinylene-2,5-diethylhexyloxy-p-phenylenevinylene and m-phenylenevinylene-2,5-diethylhexyloxy-p-phenylenevinylene by ring-opening metathesis polymn.)

PY - 2010/1/12

Y1 - 2010/1/12

N2 - p-Phenylenevinylene-2, 5-diethylhexyloxy-p-phenylenevinylene and m-phenylenevinylene-2, 5-diethylhexyloxy-p-phenylenevinylene homopolymers (3 and 4) have been prepared by the ring-opening metathesis polymerization (ROMP) of strained cyclophanedienes, initiated by the second generation Grubbs catalyst. The as-formed polymers have a backbone of alternating cis- and trans-vinylene linkages due to the opening of only one vinylene of the cyclophanediene. Irradiation with UV light results in an isomerization to an all-trans-vinylene microstructure for all polymers. The polymer chain ends remain active after complete consumption of the cyclophanediene, and block copolymers can be prepared by addition of further cyclophanediene. The optical and electronic properties of the homopolymers and block copolymers are reported. © 2009 American Chemical Society.

AB - p-Phenylenevinylene-2, 5-diethylhexyloxy-p-phenylenevinylene and m-phenylenevinylene-2, 5-diethylhexyloxy-p-phenylenevinylene homopolymers (3 and 4) have been prepared by the ring-opening metathesis polymerization (ROMP) of strained cyclophanedienes, initiated by the second generation Grubbs catalyst. The as-formed polymers have a backbone of alternating cis- and trans-vinylene linkages due to the opening of only one vinylene of the cyclophanediene. Irradiation with UV light results in an isomerization to an all-trans-vinylene microstructure for all polymers. The polymer chain ends remain active after complete consumption of the cyclophanediene, and block copolymers can be prepared by addition of further cyclophanediene. The optical and electronic properties of the homopolymers and block copolymers are reported. © 2009 American Chemical Society.

KW - Polymers Role: PEP (Physical, engineering or chemical process), PRP (Properties), SPN (Synthetic preparation), PREP (Preparation), PROC (Process) (block, diblock

KW - homopolymers and block copolymers of p-phenylenevinylene-2,5-diethylhexyloxy-p-phenylenevinylene and m-phenylenevinylene-2,5-diethylhexyloxy-p-phenylenevinylene by ring-opening metathesis polymn.)

KW - Polymerization (block

KW - Poly(arylenealkenylenes) Role: PEP (Physical, engineering or chemical process), PRP (Properties), SPN (Synthetic preparation), PREP (Preparation), PROC (Process) (block

KW - Isomerization (cis-trans, photochem.

KW - Band gap

KW - Cyclic voltammetry

KW - Glass transition temperature

KW - HOMO

KW - Heat capacity

KW - LUMO

KW - Luminescence

KW - Molecular weight

KW - Oxidation potential

KW - Polydispersity

KW - Polymer chains

KW - Reduction potential

KW - Thermal stability

KW - UV and visible spectra

KW - UV radiation (homopolymers and block copolymers of p-phenylenevinylene-2,5-diethylhexyloxy-p-phenylenevinylene and m-phenylenevinylene-2,5-diethylhexyloxy-p-phenylenevinylene by ring-opening metathesis polymn.)

KW - Poly(arylenealkenylenes) Role: PEP (Physical, engineering or chemical process), PRP (Properties), RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), PROC (Process), RACT (Reactant or reagent) (homopolymers and block copolymers of p-phenyle

KW - Polymerization (metathetic, ring-opening

KW - Band gap (optical

KW - Casting of polymeric materials (spin

KW - cyclophanediene deriv ring opening metathesis polymn photoisomerization electrochem property

U2 - 10.1021/ma901966g

DO - 10.1021/ma901966g

M3 - Article

SN - 0024-9297

VL - 43

SP - 222

EP - 232

JO - Macromolecules

JF - Macromolecules

IS - 1

ER -

Homopolymers and block copolymers of p-phenylenevinylene-2, 5-diethylhexyloxy-p-phenylenevinylene and m-phenylenevinylene-2, 5diethylhexyloxy-p-phenylenevinylene by ring-opening metathesis polymerization

Abstract

Keywords

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