How do clusters grow? The synthesis and structure of polynuclear hydroxide gallium(III) clusters

Jeremy C. Goodwin; Simon J. Teat; Sarah L. Heath

doi:10.1002/anie.200353542

How do clusters grow? The synthesis and structure of polynuclear hydroxide gallium(III) clusters

Jeremy C. Goodwin, Simon J. Teat, Sarah L. Heath

Research output: Contribution to journal › Article › peer-review

Abstract

Three complexes from one reaction: The reaction of N-(2-hydroxyethyl) iminodiacetic acid with Ga(NO3)3 yields an alkoxobridged dimer, a Ga8 cluster (see picture), and a Ga13 cluster. The structures of these complexes and the structural relationships between them are reported, and the insight they may shed on the general mechanism of cluster formation is discussed.

Original language	English
Pages (from-to)	4037-4041
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	31
DOIs	https://doi.org/10.1002/anie.200353542
Publication status	Published - 6 Aug 2004

Keywords

Aggregation
Cluster compounds
Cluster formation
Gallium

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10.1002/anie.200353542

CCDC 226694: Experimental Crystal Structure Determination
Goodwin, J. C. (Contributor), Teat, S. J. (Contributor) & Heath, S. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2005
DOI: 10.5517/cc7lwqd, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc7lwqd&sid=DataCite
Dataset
CCDC 226692: Experimental Crystal Structure Determination
Goodwin, J. C. (Contributor), Teat, S. J. (Contributor) & Heath, S. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2005
DOI: 10.5517/cc7lwnb, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc7lwnb&sid=DataCite
Dataset
CCDC 226693: Experimental Crystal Structure Determination
Goodwin, J. C. (Contributor), Teat, S. J. (Contributor) & Heath, S. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2005
DOI: 10.5517/cc7lwpc, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc7lwpc&sid=DataCite
Dataset

Cite this

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title = "How do clusters grow? The synthesis and structure of polynuclear hydroxide gallium(III) clusters",

abstract = "Three complexes from one reaction: The reaction of N-(2-hydroxyethyl) iminodiacetic acid with Ga(NO3)3 yields an alkoxobridged dimer, a Ga8 cluster (see picture), and a Ga13 cluster. The structures of these complexes and the structural relationships between them are reported, and the insight they may shed on the general mechanism of cluster formation is discussed.",

keywords = "Aggregation, Cluster compounds, Cluster formation, Gallium",

author = "Goodwin, {Jeremy C.} and Teat, {Simon J.} and Heath, {Sarah L.}",

year = "2004",

month = aug,

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doi = "10.1002/anie.200353542",

language = "English",

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pages = "4037--4041",

journal = "Angewandte Chemie. International Edition",

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TY - JOUR

T1 - How do clusters grow? The synthesis and structure of polynuclear hydroxide gallium(III) clusters

AU - Goodwin, Jeremy C.

AU - Teat, Simon J.

AU - Heath, Sarah L.

PY - 2004/8/6

Y1 - 2004/8/6

N2 - Three complexes from one reaction: The reaction of N-(2-hydroxyethyl) iminodiacetic acid with Ga(NO3)3 yields an alkoxobridged dimer, a Ga8 cluster (see picture), and a Ga13 cluster. The structures of these complexes and the structural relationships between them are reported, and the insight they may shed on the general mechanism of cluster formation is discussed.

AB - Three complexes from one reaction: The reaction of N-(2-hydroxyethyl) iminodiacetic acid with Ga(NO3)3 yields an alkoxobridged dimer, a Ga8 cluster (see picture), and a Ga13 cluster. The structures of these complexes and the structural relationships between them are reported, and the insight they may shed on the general mechanism of cluster formation is discussed.

KW - Aggregation

KW - Cluster compounds

KW - Cluster formation

KW - Gallium

U2 - 10.1002/anie.200353542

DO - 10.1002/anie.200353542

M3 - Article

VL - 43

SP - 4037

EP - 4041

JO - Angewandte Chemie. International Edition

JF - Angewandte Chemie. International Edition

SN - 1433-7851

IS - 31

ER -

How do clusters grow? The synthesis and structure of polynuclear hydroxide gallium(III) clusters

Abstract

Keywords

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Datasets

CCDC 226694: Experimental Crystal Structure Determination

CCDC 226692: Experimental Crystal Structure Determination

CCDC 226693: Experimental Crystal Structure Determination

Cite this