How does the oxidation state of palladium surfaces affect the reactivity and selectivity of direct synthesis of hydrogen peroxide from hydrogen and oxygen gases? A density functional study

Fang Wang, Chungu Xia, Samuel De Visser, Yong Wang

    Research output: Contribution to journalArticlepeer-review

    574 Downloads (Pure)

    Abstract

    Copyright © 2018 American Chemical Society. Direct synthesis of H 2 O 2 from H 2 and O 2 is an environmentally benign and atom economic process and as such is the ideal pathway in catalysis. However, currently no low-cost pathway of this kind of catalysis exists, although it would be an attractive alternative strategy to the common industrial anthraquinone method for H 2 O 2 production. Metal-based catalysts are widely employed in such a direct synthesis process but often need to be oxidized, alloyed, or supplied with additives to make them selective. To understand the metal-oxidation state in heterogeneous catalysis, we studied the selective oxidation of hydrogen by molecular oxygen on Pd(111) and PdO(101) surfaces, leading to either H 2 O 2 or H 2 O products. Our results demonstrate, for the first time, that the oxidized PdO(101) surface clearly shows better performance and selectivity, as compared to the reduced Pd(111) one. The activation barrier on the oxidized Pd surface is ca. 0.2 eV lower than the one on the reduced Pd surface. On the oxidized surface, the H 2 O 2 synthesis route is preferred, while, on the reduced surface, the H 2 O route is predominant. The decomposition of H 2 O 2 is also greatly inhibited on the oxidized surface. We analyzed the different pathways in detail through thermochemical cycles, which establishes that the oxidized surface shows weaker adsorption ability toward the reagents O 2 and H 2 , the key intermediate OOH, and also the product H 2 O 2 in comparison with the Pd(111) surface, which we believe affect the selectivity. The work presented here clearly shows that the oxidation state of metal surfaces is one of the most important factors that tunes the catalysis of a chemical reaction and can affect the selectivity and reaction patterns dramatically. ©
    Original languageEnglish
    Pages (from-to)901-910
    Number of pages10
    JournalJournal of the American Chemical Society
    Volume141
    Issue number2
    Early online date18 Dec 2018
    DOIs
    Publication statusPublished - 16 Jan 2019

    Research Beacons, Institutes and Platforms

    • Manchester Institute of Biotechnology

    Fingerprint

    Dive into the research topics of 'How does the oxidation state of palladium surfaces affect the reactivity and selectivity of direct synthesis of hydrogen peroxide from hydrogen and oxygen gases? A density functional study'. Together they form a unique fingerprint.

    Cite this