Hydrogen permeation in zirconium using a molten salt devanathan-stachurski electrochemical cell

R. A. Carvajal-Ortiz; S. B. Lyon; M. Preuss; A. Ambard

doi:10.1149/08010.1019ecst

Hydrogen permeation in zirconium using a molten salt devanathan-stachurski electrochemical cell

R. A. Carvajal-Ortiz^*, S. B. Lyon, M. Preuss, A. Ambard

^*Corresponding author for this work

Materials Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

This paper explores whether the Devanathan-Stachurski method for the measurement of hydrogen permeation in metals can be extended to measure hydrogen diffusion zirconium at temperatures corresponding to the operating conditions of nuclear power plant. The investigation consisted of two steps, the selection of suitable electrodes and (molten salt) electrolytes for high temperature use, and the subsequent investigation of hydrogen charging and hydrogen electrochemical oxidation in the chosen electrolyte. An alternative electrochemical charging and oxidation method was devised using molten hydroxide (NaOH-KOH) as a suitable electrolyte at 250-300 °C.

Original language	English
Pages (from-to)	1019-1027
Number of pages	9
Journal	ECS Transactions
Volume	80
Issue number	10
Early online date	25 Oct 2017
DOIs	https://doi.org/10.1149/08010.1019ecst
Publication status	Published - 2017
Event	232nd ECS Meeting - National Harbor, United States Duration: 1 Oct 2017 → 5 Oct 2017

Research Beacons, Institutes and Platforms

Dalton Nuclear Institute

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1149/08010.1019ecst

Cite this

@article{e2bf4e9a8f3b40b1aff793f0817c1e04,

title = "Hydrogen permeation in zirconium using a molten salt devanathan-stachurski electrochemical cell",

abstract = "This paper explores whether the Devanathan-Stachurski method for the measurement of hydrogen permeation in metals can be extended to measure hydrogen diffusion zirconium at temperatures corresponding to the operating conditions of nuclear power plant. The investigation consisted of two steps, the selection of suitable electrodes and (molten salt) electrolytes for high temperature use, and the subsequent investigation of hydrogen charging and hydrogen electrochemical oxidation in the chosen electrolyte. An alternative electrochemical charging and oxidation method was devised using molten hydroxide (NaOH-KOH) as a suitable electrolyte at 250-300 °C.",

author = "Carvajal-Ortiz, {R. A.} and Lyon, {S. B.} and M. Preuss and A. Ambard",

year = "2017",

doi = "10.1149/08010.1019ecst",

language = "English",

volume = "80",

pages = "1019--1027",

journal = "ECS Transactions",

issn = "1938-5862",

publisher = "Electrochemical Society",

number = "10",

note = "232nd ECS Meeting ; Conference date: 01-10-2017 Through 05-10-2017",

}

TY - JOUR

T1 - Hydrogen permeation in zirconium using a molten salt devanathan-stachurski electrochemical cell

AU - Carvajal-Ortiz, R. A.

AU - Lyon, S. B.

AU - Preuss, M.

AU - Ambard, A.

PY - 2017

Y1 - 2017

N2 - This paper explores whether the Devanathan-Stachurski method for the measurement of hydrogen permeation in metals can be extended to measure hydrogen diffusion zirconium at temperatures corresponding to the operating conditions of nuclear power plant. The investigation consisted of two steps, the selection of suitable electrodes and (molten salt) electrolytes for high temperature use, and the subsequent investigation of hydrogen charging and hydrogen electrochemical oxidation in the chosen electrolyte. An alternative electrochemical charging and oxidation method was devised using molten hydroxide (NaOH-KOH) as a suitable electrolyte at 250-300 °C.

AB - This paper explores whether the Devanathan-Stachurski method for the measurement of hydrogen permeation in metals can be extended to measure hydrogen diffusion zirconium at temperatures corresponding to the operating conditions of nuclear power plant. The investigation consisted of two steps, the selection of suitable electrodes and (molten salt) electrolytes for high temperature use, and the subsequent investigation of hydrogen charging and hydrogen electrochemical oxidation in the chosen electrolyte. An alternative electrochemical charging and oxidation method was devised using molten hydroxide (NaOH-KOH) as a suitable electrolyte at 250-300 °C.

UR - http://www.scopus.com/inward/record.url?scp=85046116165&partnerID=8YFLogxK

U2 - 10.1149/08010.1019ecst

DO - 10.1149/08010.1019ecst

M3 - Article

AN - SCOPUS:85046116165

SN - 1938-5862

VL - 80

SP - 1019

EP - 1027

JO - ECS Transactions

JF - ECS Transactions

IS - 10

T2 - 232nd ECS Meeting

Y2 - 1 October 2017 through 5 October 2017

ER -

Hydrogen permeation in zirconium using a molten salt devanathan-stachurski electrochemical cell

Abstract

Research Beacons, Institutes and Platforms

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this