TY - JOUR
T1 - Hydrogen storage in liquid organic hydride: Selectivity of MCH dehydrogenation over monometallic and bimetallic Pt catalysts
AU - Alhumaidan, Faisal
AU - Tsakiris, Dimos
AU - Cresswell, David
AU - Garforth, Arthur
N1 - CAN 160:162584 Electrochemical, Radiational, and Thermal Energy Technology 1344-28-1 (Aluminum oxide (Al2O3)); 7440-06-4 (Platinum); 7440-15-5 (Rhenium) Role: CAT (Catalyst use), PEP (Physical, engineering or chemical process), PRP (Properties), TEM (Technical or engineered material use), PROC (Process), USES (Uses) (hydrogen storage in liq. org. hydride and selectivity of methylcyclohexane dehydrogenation over monometallic and bimetallic platinum catalysts); 71-43-2 (Benzene); 85-01-8 (Phenanthrene); 95-47-6 (Ortho-xylene); 106-42-3; 108-38-3; 108-87-2 (Methylcyclohexane); 108-88-3 (Toluene); 142-82-5 (Heptane); 605-39-0 (2,2'-Dimethylbiphenyl); 611-43-8 (2,3'-Dimethylbiphenyl); 611-61-0 (2,4'-Dimethylbiphenyl); 612-75-9 (3,3'-Dimethylbiphenyl); 613-33-2 (4,4'-Dimethylbiphenyl); 1335-86-0 (Methylcyclohexene); 1640-89-7 (Ethylcyclopentane); 7383-90-6 (3,4'-Dimethylbiphenyl); 28652-72-4 (Methylbiphenyl); 28729-52-4 (Dimethylcyclopentane); 30640-46-1 (Methylcyclohexadiene) Role: TEM (Technical or engineered material use), USES (Uses) (hydrogen storage in liq. org. hydride and selectivity of methylcyclohexane dehydrogenation over monometallic and bimetallic platinum catalysts)
PY - 2013
Y1 - 2013
N2 - Hydrogen storage for mobile and stationary applications is an expanding research topic. One of the more promising storage techniques relies on the reversibility, high selectivity, and high hydrogen d. of liq. org. hydrides, in particular methylcyclohexane (MCH). Catalyst evaluation for MCH dehydrogenation to toluene is based on three catalytic parameters: activity, selectivity, and stability. Current catalysts, optimized for catalytic reforming, do not meet the targeted arom. selectivity (+99%) for MCH dehydrogenation. Therefore, a range of Pt catalysts was prepd. and compared with com. available catalysts in a fixed-bed reactor under operating conditions suitable for mobile and stationary applications. The best overall performance was realized by a particular monometallic Pt catalyst. This catalyst showed superior activity, selectivity, and stability compared with other prepd. and com. catalysts. As an effort to further enhance the arom. selectivity, this study identified the main side-reactions assocd. with MCH dehydrogenation, the effect of operating parameters on byproduct yields, and the effect of catalyst deactivation on long-term selectivity. [on SciFinder(R)]
AB - Hydrogen storage for mobile and stationary applications is an expanding research topic. One of the more promising storage techniques relies on the reversibility, high selectivity, and high hydrogen d. of liq. org. hydrides, in particular methylcyclohexane (MCH). Catalyst evaluation for MCH dehydrogenation to toluene is based on three catalytic parameters: activity, selectivity, and stability. Current catalysts, optimized for catalytic reforming, do not meet the targeted arom. selectivity (+99%) for MCH dehydrogenation. Therefore, a range of Pt catalysts was prepd. and compared with com. available catalysts in a fixed-bed reactor under operating conditions suitable for mobile and stationary applications. The best overall performance was realized by a particular monometallic Pt catalyst. This catalyst showed superior activity, selectivity, and stability compared with other prepd. and com. catalysts. As an effort to further enhance the arom. selectivity, this study identified the main side-reactions assocd. with MCH dehydrogenation, the effect of operating parameters on byproduct yields, and the effect of catalyst deactivation on long-term selectivity. [on SciFinder(R)]
KW - Reactors (fixed-bed
KW - hydrogen storage in liq. org. hydride and selectivity of methylcyclohexane dehydrogenation over monometallic and bimetallic platinum catalysts)
KW - Catalysts
KW - Dehydrogenation
KW - Hydrogen storage materials
KW - Impregnation
KW - Steam reforming (hydrogen storage in liq. org. hydride and selectivity of methylcyclohexane dehydrogenation over monometallic and bimetallic platinum catalysts)
KW - Paraffin oils Role: TEM (Technical or engineered material use), USES (Uses) (hydrogen storage in liq. org. hydride and selectivity of methylcyclohexane dehydrogenation over monometallic and bimetallic platinum catalysts)
KW - hydrogen storage liq org hydride methylcyclohexane dehydrogenation platinum catalyst
U2 - 10.1016/j.ijhydene.2013.08.067
DO - 10.1016/j.ijhydene.2013.08.067
M3 - Article
SN - 0360-3199
VL - 38
SP - 14010
EP - 14026
JO - Int. J. Hydrogen Energy
JF - Int. J. Hydrogen Energy
IS - 32
ER -
