Hydroxylamine Derivatives as Nitrogen-Radical Precursors in Visible-Light Photochemistry

Jacob Davies; Sara P. Morcillo; James J. Douglas; Daniele Leonori

doi:10.1002/chem.201801655

Hydroxylamine Derivatives as Nitrogen-Radical Precursors in Visible-Light Photochemistry

Jacob Davies, Sara P. Morcillo, James J. Douglas, Daniele Leonori

AstraZeneca

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Abstract

In recent years, hydroxylamines derivatives have been exploited as nitrogen‐radical precursors in visible‐light photochemistry. Their ability to serve as electrophores in redox chemistry has propelled the development of many novel transformations. Fundamental mechanistic aspects as well as the importance in the preparation of nitrogen‐containing molecules will be highlighted.

Original language	English
Journal	Chemistry - A European Journal
Early online date	22 May 2018
DOIs	https://doi.org/10.1002/chem.201801655
Publication status	Published - 2018

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10.1002/chem.201801655

Concept Article - RevisedAccepted author manuscript, 2.32 MB

http://doi.wiley.com/10.1002/chem.201801655

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title = "Hydroxylamine Derivatives as Nitrogen-Radical Precursors in Visible-Light Photochemistry",

abstract = "In recent years, hydroxylamines derivatives have been exploited as nitrogen‐radical precursors in visible‐light photochemistry. Their ability to serve as electrophores in redox chemistry has propelled the development of many novel transformations. Fundamental mechanistic aspects as well as the importance in the preparation of nitrogen‐containing molecules will be highlighted.",

author = "Jacob Davies and Morcillo, \{Sara P.\} and Douglas, \{James J.\} and Daniele Leonori",

year = "2018",

doi = "10.1002/chem.201801655",

language = "English",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "John Wiley \& Sons Ltd",

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T1 - Hydroxylamine Derivatives as Nitrogen-Radical Precursors in Visible-Light Photochemistry

AU - Davies, Jacob

AU - Morcillo, Sara P.

AU - Douglas, James J.

AU - Leonori, Daniele

PY - 2018

Y1 - 2018

N2 - In recent years, hydroxylamines derivatives have been exploited as nitrogen‐radical precursors in visible‐light photochemistry. Their ability to serve as electrophores in redox chemistry has propelled the development of many novel transformations. Fundamental mechanistic aspects as well as the importance in the preparation of nitrogen‐containing molecules will be highlighted.

AB - In recent years, hydroxylamines derivatives have been exploited as nitrogen‐radical precursors in visible‐light photochemistry. Their ability to serve as electrophores in redox chemistry has propelled the development of many novel transformations. Fundamental mechanistic aspects as well as the importance in the preparation of nitrogen‐containing molecules will be highlighted.

U2 - 10.1002/chem.201801655

DO - 10.1002/chem.201801655

M3 - Article

SN - 0947-6539

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

ER -

Hydroxylamine Derivatives as Nitrogen-Radical Precursors in Visible-Light Photochemistry

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