Imine chloroboration: Reaction of boron trichloride with a bulky diazadiene gives not a diazaborolium salt, but a 2,4,5 trichloro-1,3,2-diazaborolidine

F. S. Mair; R. Manning; R. G. Pritchard; J. E. Warren

doi:10.1039/b101580j

Imine chloroboration: Reaction of boron trichloride with a bulky diazadiene gives not a diazaborolium salt, but a 2,4,5 trichloro-1,3,2-diazaborolidine

F. S. Mair, R. Manning, R. G. Pritchard, J. E. Warren

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of N,N′-bis(2,6-diisopropylphenyl)-1,4-diazadiene with BCl3 in hexane gave the crystalline product of double chloroboration, N,N′-bis(2,6-diisopropylphenyl)2,4,5-trichloro-1,3,2-diazaborolidine, which was characterised by single crystal X-ray diffraction, microanalysis and multinuclear NMR spectroscopy.

Original language	English
Pages (from-to)	1136-1137
Number of pages	1
Journal	Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/b101580j
Publication status	Published - 21 Jun 2001

Keywords

{BROMIDE
DIMETHYLBORON
DIMETHYLBORON} {BROMIDE
{DIMETHYLBORON} {BROMIDE
HALOBORATION

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10.1039/b101580j

http://www.rsc.org/delivery/_ArticleLinking/DisplayArticleForFree.cfm?doi=b101580j&JournalCode=CC

CCDC 160079: Experimental Crystal Structure Determination
Mair, F. (Contributor), Manning, R. (Contributor), Pritchard, R. (Contributor) & Warren, J. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2001
DOI: 10.5517/cc5ckvx, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc5ckvx&sid=DataCite
Dataset

Cite this

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title = "Imine chloroboration: Reaction of boron trichloride with a bulky diazadiene gives not a diazaborolium salt, but a 2,4,5 trichloro-1,3,2-diazaborolidine",

abstract = "Reaction of N,N′-bis(2,6-diisopropylphenyl)-1,4-diazadiene with BCl3 in hexane gave the crystalline product of double chloroboration, N,N′-bis(2,6-diisopropylphenyl)2,4,5-trichloro-1,3,2-diazaborolidine, which was characterised by single crystal X-ray diffraction, microanalysis and multinuclear NMR spectroscopy.",

keywords = "{BROMIDE, DIMETHYLBORON, DIMETHYLBORON} {BROMIDE, {DIMETHYLBORON} {BROMIDE, HALOBORATION",

author = "Mair, {F. S.} and R. Manning and Pritchard, {R. G.} and Warren, {J. E.}",

note = "12",

year = "2001",

month = jun,

day = "21",

doi = "10.1039/b101580j",

language = "English",

pages = "1136--1137",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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AU - Mair, F. S.

AU - Manning, R.

AU - Pritchard, R. G.

AU - Warren, J. E.

N1 - 12

PY - 2001/6/21

Y1 - 2001/6/21

N2 - Reaction of N,N′-bis(2,6-diisopropylphenyl)-1,4-diazadiene with BCl3 in hexane gave the crystalline product of double chloroboration, N,N′-bis(2,6-diisopropylphenyl)2,4,5-trichloro-1,3,2-diazaborolidine, which was characterised by single crystal X-ray diffraction, microanalysis and multinuclear NMR spectroscopy.

AB - Reaction of N,N′-bis(2,6-diisopropylphenyl)-1,4-diazadiene with BCl3 in hexane gave the crystalline product of double chloroboration, N,N′-bis(2,6-diisopropylphenyl)2,4,5-trichloro-1,3,2-diazaborolidine, which was characterised by single crystal X-ray diffraction, microanalysis and multinuclear NMR spectroscopy.

KW - {BROMIDE

KW - DIMETHYLBORON

KW - DIMETHYLBORON} {BROMIDE

KW - {DIMETHYLBORON} {BROMIDE

KW - HALOBORATION

U2 - 10.1039/b101580j

DO - 10.1039/b101580j

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SN - 1359-7345

SP - 1136

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JO - Chemical Communications

JF - Chemical Communications

IS - 12

ER -

Imine chloroboration: Reaction of boron trichloride with a bulky diazadiene gives not a diazaborolium salt, but a 2,4,5 trichloro-1,3,2-diazaborolidine

Abstract

Keywords

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Datasets

CCDC 160079: Experimental Crystal Structure Determination

Cite this