In-situ coordination chemistry within cobalt-containing phthalocyanine nanoporous crystals

C. Grazia Bezzu; Benson M. Kariuki; Madeleine Helliwell; Floriana Tuna; John E. Warren; David R. Allan; Neil B. Mckeown

doi:10.1039/c2ce26463c

In-situ coordination chemistry within cobalt-containing phthalocyanine nanoporous crystals

C. Grazia Bezzu, Benson M. Kariuki, Madeleine Helliwell, Floriana Tuna, John E. Warren, David R. Allan, Neil B. Mckeown

Science & Technology Facilities Council (STFC)

Research output: Contribution to journal › Article › peer-review

Abstract

Nanoporous crystals formed by the cobalt complex of 2,3,9,10,16,17,23,24- octa(2′,6′-di-iso-propyphenoxy)phthalocyanine were used to demonstrate in situ coordination chemistry by single-crystal-to-single-crystal transformations. Ligand exchange, including the introduction of imidazole with the apparent simultaneous oxidation of the metal centre, was readily achieved by simply adding the new ligand into the solvent in contact with the Phthalocyanine nanoporous crystals (PNCs). In addition, chloride and bromide axial ligands were introduced by the use of aqueous hydrochloric, hydrobromic acid or bromine as reagents. © 2013 The Royal Society of Chemistry.

Original language	English
Pages (from-to)	1545-1550
Number of pages	5
Journal	CrystEngComm
Volume	15
Issue number	8
DOIs	https://doi.org/10.1039/c2ce26463c
Publication status	Published - 28 Feb 2013

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10.1039/c2ce26463c

CCDC 900369: Experimental Crystal Structure Determination
Bezzu, C. G. (Contributor), Kariuki, B. M. (Contributor), Helliwell, M. (Contributor), Tuna, F. (Contributor), Warren, J. (Contributor), Allan, D. R. (Contributor) & Mckeown, N. B. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2013
DOI: 10.5517/ccz6x57, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccz6x57&sid=DataCite
Dataset
CCDC 900367: Experimental Crystal Structure Determination
Bezzu, C. G. (Contributor), Kariuki, B. M. (Contributor), Helliwell, M. (Contributor), Tuna, F. (Contributor), Warren, J. (Contributor), Allan, D. R. (Contributor) & Mckeown, N. B. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2013
DOI: 10.5517/ccz6x35, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccz6x35&sid=DataCite
Dataset
CCDC 900380: Experimental Crystal Structure Determination
Bezzu, C. G. (Contributor), Kariuki, B. M. (Contributor), Helliwell, M. (Contributor), Tuna, F. (Contributor), Warren, J. (Contributor), Allan, D. R. (Contributor) & Mckeown, N. B. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2013
DOI: 10.5517/ccz6xjl, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccz6xjl&sid=DataCite
Dataset

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@article{00a799c3e45642328702ec50402b8701,

title = "In-situ coordination chemistry within cobalt-containing phthalocyanine nanoporous crystals",

abstract = "Nanoporous crystals formed by the cobalt complex of 2,3,9,10,16,17,23,24- octa(2′,6′-di-iso-propyphenoxy)phthalocyanine were used to demonstrate in situ coordination chemistry by single-crystal-to-single-crystal transformations. Ligand exchange, including the introduction of imidazole with the apparent simultaneous oxidation of the metal centre, was readily achieved by simply adding the new ligand into the solvent in contact with the Phthalocyanine nanoporous crystals (PNCs). In addition, chloride and bromide axial ligands were introduced by the use of aqueous hydrochloric, hydrobromic acid or bromine as reagents. {\textcopyright} 2013 The Royal Society of Chemistry.",

author = "Bezzu, {C. Grazia} and Kariuki, {Benson M.} and Madeleine Helliwell and Floriana Tuna and Warren, {John E.} and Allan, {David R.} and Mckeown, {Neil B.}",

year = "2013",

month = feb,

day = "28",

doi = "10.1039/c2ce26463c",

language = "English",

volume = "15",

pages = "1545--1550",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "8",

}

TY - JOUR

T1 - In-situ coordination chemistry within cobalt-containing phthalocyanine nanoporous crystals

AU - Bezzu, C. Grazia

AU - Kariuki, Benson M.

AU - Helliwell, Madeleine

AU - Tuna, Floriana

AU - Warren, John E.

AU - Allan, David R.

AU - Mckeown, Neil B.

PY - 2013/2/28

Y1 - 2013/2/28

N2 - Nanoporous crystals formed by the cobalt complex of 2,3,9,10,16,17,23,24- octa(2′,6′-di-iso-propyphenoxy)phthalocyanine were used to demonstrate in situ coordination chemistry by single-crystal-to-single-crystal transformations. Ligand exchange, including the introduction of imidazole with the apparent simultaneous oxidation of the metal centre, was readily achieved by simply adding the new ligand into the solvent in contact with the Phthalocyanine nanoporous crystals (PNCs). In addition, chloride and bromide axial ligands were introduced by the use of aqueous hydrochloric, hydrobromic acid or bromine as reagents. © 2013 The Royal Society of Chemistry.

AB - Nanoporous crystals formed by the cobalt complex of 2,3,9,10,16,17,23,24- octa(2′,6′-di-iso-propyphenoxy)phthalocyanine were used to demonstrate in situ coordination chemistry by single-crystal-to-single-crystal transformations. Ligand exchange, including the introduction of imidazole with the apparent simultaneous oxidation of the metal centre, was readily achieved by simply adding the new ligand into the solvent in contact with the Phthalocyanine nanoporous crystals (PNCs). In addition, chloride and bromide axial ligands were introduced by the use of aqueous hydrochloric, hydrobromic acid or bromine as reagents. © 2013 The Royal Society of Chemistry.

U2 - 10.1039/c2ce26463c

DO - 10.1039/c2ce26463c

M3 - Article

VL - 15

SP - 1545

EP - 1550

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 8

ER -

In-situ coordination chemistry within cobalt-containing phthalocyanine nanoporous crystals

Abstract

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Datasets

CCDC 900369: Experimental Crystal Structure Determination

CCDC 900367: Experimental Crystal Structure Determination

CCDC 900380: Experimental Crystal Structure Determination

Cite this