TY - GEN
T1 - In-situ X-ray studies of clean catalytic technologies
AU - Lee, Adam F.
AU - Ellis, Christine V.
AU - Newton, Mark A.
AU - Parlett, Christopher M.
AU - Wilson, Karen
PY - 2011/12/1
Y1 - 2011/12/1
N2 - The rational design of new heterogeneous catalysts for clean chemical technologies can be accelerated by molecular level insight into surface chemical processes. In-situ methodologies, able to provide time-resolved and/or pressure dependent information on the evolution of reacting adsorbed layers over catalytically relevant surfaces, are therefore of especial interest. Here we discuss the application of in-situ XPS and in-situ, synchronous DRIFTS/MS/XAS methodologies to elucidate the active site in Pd-catalyzed, selective aerobic oxidation of allylic alcohols.
AB - The rational design of new heterogeneous catalysts for clean chemical technologies can be accelerated by molecular level insight into surface chemical processes. In-situ methodologies, able to provide time-resolved and/or pressure dependent information on the evolution of reacting adsorbed layers over catalytically relevant surfaces, are therefore of especial interest. Here we discuss the application of in-situ XPS and in-situ, synchronous DRIFTS/MS/XAS methodologies to elucidate the active site in Pd-catalyzed, selective aerobic oxidation of allylic alcohols.
UR - http://www.scopus.com/inward/record.url?scp=84860203193&partnerID=8YFLogxK
U2 - 10.1557/opl.2011.1170
DO - 10.1557/opl.2011.1170
M3 - Conference contribution
AN - SCOPUS:84860203193
SN - 9781618395542
VL - 1351
T3 - Materials Research Society Symposium Proceedings
SP - 32
EP - 37
BT - Surfaces and Nanomaterials for Catalysis through In-Situ or Ex-Situ Studies
T2 - 2011 MRS Spring Meeting
Y2 - 25 April 2011 through 29 April 2011
ER -