Influence of pressure on a dysprosocenium single molecule magnet

Vijay Parmar; Andreas Munch Thiel; Rizwan Nabi; Gemma Kate Gransbury; Marie Norre; Peter Evans; Sophie C. Corner; Jonathan Skelton; Nicholas F Chilton; David P Mills; Jacob Overgaard

doi:10.1039/D2CC06722F

Influence of pressure on a dysprosocenium single molecule magnet

Vijay Parmar, Andreas Munch Thiel, Rizwan Nabi, Gemma Kate Gransbury, Marie Norre, Peter Evans, Sophie C. Corner, Jonathan Skelton, Nicholas F Chilton, David P Mills, Jacob Overgaard

Research output: Contribution to journal › Article › peer-review

Abstract

The effects of external pressure on a high-performing dysprosocenium single-molecule magnet are investigated using a combination of X-ray diffraction, magnetometry and theoretical calculations. The effective energy barrier (Ueff) decreases from ca. 1300 cm-1 at ambient pressure to ca. 1125 cm-1 at 3 GPa. Our results indicate that compression 1 GPa increases via Raman relaxation and/or quantum tunnelling of magnetisation.

Original language	English
Journal	Chemical Communications
Early online date	6 Feb 2023
DOIs	https://doi.org/10.1039/D2CC06722F
Publication status	E-pub ahead of print - 6 Feb 2023

Access to Document

10.1039/D2CC06722FLicence: CC BY

http://pubs.rsc.org/en/Content/ArticleLanding/2023/CC/D2CC06722F

Influence of pressure on a dysprosocenium single molecule magnet
Parmar, V. S. (Creator), Chilton, N. (Contributor), Mills, D. (Contributor) & Skelton, J. (Contributor), Mendeley Data, 13 Feb 2023
DOI: 10.17632/sfmn8566th.1, https://data.mendeley.com/datasets/sfmn8566th
Dataset

Cite this

@article{ebffd991d30f41da94eb78b5d83912e5,

title = "Influence of pressure on a dysprosocenium single molecule magnet",

abstract = "The effects of external pressure on a high-performing dysprosocenium single-molecule magnet are investigated using a combination of X-ray diffraction, magnetometry and theoretical calculations. The effective energy barrier (Ueff) decreases from ca. 1300 cm-1 at ambient pressure to ca. 1125 cm-1 at 3 GPa. Our results indicate that compression 1 GPa increases via Raman relaxation and/or quantum tunnelling of magnetisation.",

author = "Vijay Parmar and Thiel, {Andreas Munch} and Rizwan Nabi and Gransbury, {Gemma Kate} and Marie Norre and Peter Evans and Corner, {Sophie C.} and Jonathan Skelton and Chilton, {Nicholas F} and Mills, {David P} and Jacob Overgaard",

year = "2023",

month = feb,

day = "6",

doi = "10.1039/D2CC06722F",

language = "English",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

}

TY - JOUR

T1 - Influence of pressure on a dysprosocenium single molecule magnet

AU - Parmar, Vijay

AU - Thiel, Andreas Munch

AU - Nabi, Rizwan

AU - Gransbury, Gemma Kate

AU - Norre, Marie

AU - Evans, Peter

AU - Corner, Sophie C.

AU - Skelton, Jonathan

AU - Chilton, Nicholas F

AU - Mills, David P

AU - Overgaard, Jacob

PY - 2023/2/6

Y1 - 2023/2/6

N2 - The effects of external pressure on a high-performing dysprosocenium single-molecule magnet are investigated using a combination of X-ray diffraction, magnetometry and theoretical calculations. The effective energy barrier (Ueff) decreases from ca. 1300 cm-1 at ambient pressure to ca. 1125 cm-1 at 3 GPa. Our results indicate that compression 1 GPa increases via Raman relaxation and/or quantum tunnelling of magnetisation.

AB - The effects of external pressure on a high-performing dysprosocenium single-molecule magnet are investigated using a combination of X-ray diffraction, magnetometry and theoretical calculations. The effective energy barrier (Ueff) decreases from ca. 1300 cm-1 at ambient pressure to ca. 1125 cm-1 at 3 GPa. Our results indicate that compression 1 GPa increases via Raman relaxation and/or quantum tunnelling of magnetisation.

U2 - 10.1039/D2CC06722F

DO - 10.1039/D2CC06722F

M3 - Article

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

ER -

Influence of pressure on a dysprosocenium single molecule magnet

Abstract

Access to Document

Fingerprint

Datasets

Influence of pressure on a dysprosocenium single molecule magnet

Cite this