Influence of structural and dielectric anisotropy on the dielectrophoresis of single-walled carbon nanotubes

Sabine Blatt, Frank Hennrich, Hilbert V. Löhneysen, Manfred M. Kappes, Aravind Vijayaraghavan, Ralph Krupke

    Research output: Contribution to journalArticlepeer-review

    Abstract

    We report on a carbon nanotube network which is composed of aligned metallic and randomly oriented semiconducting single-walled carbon nanotubes. The material is formed by using a novel radio frequency dielectrophoresis setup, which generates very large dielectrophoretic force fields and allows dielectrophoretic assembling of nanotube films up to 100 nm thickness. Polarization dependent absorption measurements provide experimental evidence for the electronic type specific alignment behavior. We explain the experimental data with an advanced model for nanotube dielectrophoresis, which explicitly takes into account both the longitudinal and transversal polarizability. On the basis of this model, we calculate the dielectrophoretic force fields and show that semiconducting nanotubes deposit under very large fields due to their transversal polarizability even for high field frequencies. © 2007 American Chemical Society.
    Original languageEnglish
    Pages (from-to)1960-1966
    Number of pages6
    JournalNano Letters
    Volume7
    Issue number7
    DOIs
    Publication statusPublished - Jul 2007

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