Influence of the N-bridging ligand on magnetic relaxation in an organometallic dysprosium single-molecule magnet

Richard A. Layfield; Joseph J W McDouall; Scott A. Sulway; Floriana Tuna; David Collison; Richard E P Winpenny

doi:10.1002/chem.201000158

Influence of the N-bridging ligand on magnetic relaxation in an organometallic dysprosium single-molecule magnet

Richard A. Layfield, Joseph J W McDouall, Scott A. Sulway, Floriana Tuna, David Collison, Richard E P Winpenny

Research output: Contribution to journal › Article › peer-review

Abstract

Organometallic single-molecule magnet: Studies of two dimeric organometallic dysprosium compounds reveal one to be the first organometallic single-molecule magnet (see picture). A comparison of the magnetic properties and electronic structures of the two compounds shows that Dy-Dy interactions have a profound influence on the dynamic magnetic behaviour, while having little effect on the static magnetic measurements. (Chemical Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

Original language	English
Pages (from-to)	4442-4446
Number of pages	4
Journal	Chemistry - A European Journal
Volume	16
Issue number	15
DOIs	https://doi.org/10.1002/chem.201000158
Publication status	Published - 19 Apr 2010

Keywords

Density functional calculations
Dysprosium
Lanthanides
Magnetic properties
Organometallics singlemolecule magnetism

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10.1002/chem.201000158

http://www3.interscience.wiley.com/cgi-bin/fulltext/123322071/PDFSTART

CCDC 750397: Experimental Crystal Structure Determination
Layfield, R. (Contributor), Mcdouall, J. (Contributor), Sulway, S. A. (Contributor), Tuna, F. (Contributor), Collison, D. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2009
DOI: 10.5517/cct5vc5, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cct5vc5&sid=DataCite
Dataset

Cite this

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title = "Influence of the N-bridging ligand on magnetic relaxation in an organometallic dysprosium single-molecule magnet",

abstract = "Organometallic single-molecule magnet: Studies of two dimeric organometallic dysprosium compounds reveal one to be the first organometallic single-molecule magnet (see picture). A comparison of the magnetic properties and electronic structures of the two compounds shows that Dy-Dy interactions have a profound influence on the dynamic magnetic behaviour, while having little effect on the static magnetic measurements. (Chemical Figure Presented) {\textcopyright} 2010 Wiley-VCH Verlag GmbH & Co. KGaA.",

keywords = "Density functional calculations, Dysprosium, Lanthanides, Magnetic properties, Organometallics singlemolecule magnetism",

author = "Layfield, {Richard A.} and McDouall, {Joseph J W} and Sulway, {Scott A.} and Floriana Tuna and David Collison and Winpenny, {Richard E P}",

year = "2010",

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doi = "10.1002/chem.201000158",

language = "English",

volume = "16",

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T1 - Influence of the N-bridging ligand on magnetic relaxation in an organometallic dysprosium single-molecule magnet

AU - Layfield, Richard A.

AU - McDouall, Joseph J W

AU - Sulway, Scott A.

AU - Tuna, Floriana

AU - Collison, David

AU - Winpenny, Richard E P

PY - 2010/4/19

Y1 - 2010/4/19

N2 - Organometallic single-molecule magnet: Studies of two dimeric organometallic dysprosium compounds reveal one to be the first organometallic single-molecule magnet (see picture). A comparison of the magnetic properties and electronic structures of the two compounds shows that Dy-Dy interactions have a profound influence on the dynamic magnetic behaviour, while having little effect on the static magnetic measurements. (Chemical Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

AB - Organometallic single-molecule magnet: Studies of two dimeric organometallic dysprosium compounds reveal one to be the first organometallic single-molecule magnet (see picture). A comparison of the magnetic properties and electronic structures of the two compounds shows that Dy-Dy interactions have a profound influence on the dynamic magnetic behaviour, while having little effect on the static magnetic measurements. (Chemical Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

KW - Density functional calculations

KW - Dysprosium

KW - Lanthanides

KW - Magnetic properties

KW - Organometallics singlemolecule magnetism

U2 - 10.1002/chem.201000158

DO - 10.1002/chem.201000158

M3 - Article

SN - 0947-6539

VL - 16

SP - 4442

EP - 4446

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 15

ER -

Influence of the N-bridging ligand on magnetic relaxation in an organometallic dysprosium single-molecule magnet

Abstract

Keywords

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CCDC 750397: Experimental Crystal Structure Determination

Cite this