Interpolymer complexes of poly(acrylic acid) nanogels with some non-ionic polymers in aqueous solutions

Vitaliy Khutoryanskiy; Zauresh S. Nurkeeva; Vitaliy V. Khutoryanskiy; Grigoriy A. Mun; Asem B. Bitekenova; Slawomir Kadlubowski; Yulia A. Shilina; Piotr Ulanski; Janusz M. Rosiak

doi:10.1016/j.colsurfa.2004.01.026

Interpolymer complexes of poly(acrylic acid) nanogels with some non-ionic polymers in aqueous solutions

Vitaliy Khutoryanskiy, Zauresh S. Nurkeeva, Vitaliy V. Khutoryanskiy, Grigoriy A. Mun, Asem B. Bitekenova, Slawomir Kadlubowski, Yulia A. Shilina, Piotr Ulanski, Janusz M. Rosiak

Research output: Contribution to journal › Article › peer-review

Abstract

Formation of interpolymer complexes (IPC) between the nanogels of poly(acrylic acid) (PAA) and linear polyvinylpyrrolidone (PVP), poly(vinyl methyl ether) (PVME) and poly(vinyl ether of ethyleneglycol) (PVEEG) in aqueous solutions has been studied by viscometric, turbidimetric and FTIR spectroscopic methods. It was found that in the course of complex formation the nanogels are characterised by lower amplitude of conformation changes in comparison with linear PAA. The critical pH values of complexation were determined. It was shown that the nanogels have lower complexation ability than linear PAA with respect to non-ionic polymers because of steric reasons caused by intramolecular cross-linked structure. © 2004 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	141-146
Number of pages	5
Journal	Colloids and Surfaces A: Physicochemical and Engineering Aspects
Volume	236
Issue number	1-3
DOIs	https://doi.org/10.1016/j.colsurfa.2004.01.026
Publication status	Published - 1 Apr 2004

Keywords

Critical pH
Hydrogen bonding
Interpolymer complexes
Nanogels
Poly(acrylic acid)

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10.1016/j.colsurfa.2004.01.026

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Khutoryanskiy, V., Nurkeeva, Z. S., Khutoryanskiy, V. V., Mun, G. A., Bitekenova, A. B., Kadlubowski, S., Shilina, Y. A., Ulanski, P., & Rosiak, J. M. (2004). Interpolymer complexes of poly(acrylic acid) nanogels with some non-ionic polymers in aqueous solutions. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 236(1-3), 141-146. https://doi.org/10.1016/j.colsurfa.2004.01.026

@article{a2c7c24af6c44810a42aa6bf395f7b28,

title = "Interpolymer complexes of poly(acrylic acid) nanogels with some non-ionic polymers in aqueous solutions",

abstract = "Formation of interpolymer complexes (IPC) between the nanogels of poly(acrylic acid) (PAA) and linear polyvinylpyrrolidone (PVP), poly(vinyl methyl ether) (PVME) and poly(vinyl ether of ethyleneglycol) (PVEEG) in aqueous solutions has been studied by viscometric, turbidimetric and FTIR spectroscopic methods. It was found that in the course of complex formation the nanogels are characterised by lower amplitude of conformation changes in comparison with linear PAA. The critical pH values of complexation were determined. It was shown that the nanogels have lower complexation ability than linear PAA with respect to non-ionic polymers because of steric reasons caused by intramolecular cross-linked structure. {\textcopyright} 2004 Elsevier B.V. All rights reserved.",

keywords = "Critical pH, Hydrogen bonding, Interpolymer complexes, Nanogels, Poly(acrylic acid)",

author = "Vitaliy Khutoryanskiy and Nurkeeva, {Zauresh S.} and Khutoryanskiy, {Vitaliy V.} and Mun, {Grigoriy A.} and Bitekenova, {Asem B.} and Slawomir Kadlubowski and Shilina, {Yulia A.} and Piotr Ulanski and Rosiak, {Janusz M.}",

year = "2004",

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day = "1",

doi = "10.1016/j.colsurfa.2004.01.026",

language = "English",

volume = "236",

pages = "141--146",

journal = "Colloids and Surfaces A: Physicochemical and Engineering Aspects",

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publisher = "Elsevier BV",

number = "1-3",

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Khutoryanskiy, V, Nurkeeva, ZS, Khutoryanskiy, VV, Mun, GA, Bitekenova, AB, Kadlubowski, S, Shilina, YA, Ulanski, P & Rosiak, JM 2004, 'Interpolymer complexes of poly(acrylic acid) nanogels with some non-ionic polymers in aqueous solutions', Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 236, no. 1-3, pp. 141-146. https://doi.org/10.1016/j.colsurfa.2004.01.026

TY - JOUR

T1 - Interpolymer complexes of poly(acrylic acid) nanogels with some non-ionic polymers in aqueous solutions

AU - Khutoryanskiy, Vitaliy

AU - Nurkeeva, Zauresh S.

AU - Khutoryanskiy, Vitaliy V.

AU - Mun, Grigoriy A.

AU - Bitekenova, Asem B.

AU - Kadlubowski, Slawomir

AU - Shilina, Yulia A.

AU - Ulanski, Piotr

AU - Rosiak, Janusz M.

PY - 2004/4/1

Y1 - 2004/4/1

N2 - Formation of interpolymer complexes (IPC) between the nanogels of poly(acrylic acid) (PAA) and linear polyvinylpyrrolidone (PVP), poly(vinyl methyl ether) (PVME) and poly(vinyl ether of ethyleneglycol) (PVEEG) in aqueous solutions has been studied by viscometric, turbidimetric and FTIR spectroscopic methods. It was found that in the course of complex formation the nanogels are characterised by lower amplitude of conformation changes in comparison with linear PAA. The critical pH values of complexation were determined. It was shown that the nanogels have lower complexation ability than linear PAA with respect to non-ionic polymers because of steric reasons caused by intramolecular cross-linked structure. © 2004 Elsevier B.V. All rights reserved.

AB - Formation of interpolymer complexes (IPC) between the nanogels of poly(acrylic acid) (PAA) and linear polyvinylpyrrolidone (PVP), poly(vinyl methyl ether) (PVME) and poly(vinyl ether of ethyleneglycol) (PVEEG) in aqueous solutions has been studied by viscometric, turbidimetric and FTIR spectroscopic methods. It was found that in the course of complex formation the nanogels are characterised by lower amplitude of conformation changes in comparison with linear PAA. The critical pH values of complexation were determined. It was shown that the nanogels have lower complexation ability than linear PAA with respect to non-ionic polymers because of steric reasons caused by intramolecular cross-linked structure. © 2004 Elsevier B.V. All rights reserved.

KW - Critical pH

KW - Hydrogen bonding

KW - Interpolymer complexes

KW - Nanogels

KW - Poly(acrylic acid)

U2 - 10.1016/j.colsurfa.2004.01.026

DO - 10.1016/j.colsurfa.2004.01.026

M3 - Article

SN - 0927-7757

VL - 236

SP - 141

EP - 146

JO - Colloids and Surfaces A: Physicochemical and Engineering Aspects

JF - Colloids and Surfaces A: Physicochemical and Engineering Aspects

IS - 1-3

ER -

Interpolymer complexes of poly(acrylic acid) nanogels with some non-ionic polymers in aqueous solutions

Abstract

Keywords

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