Interpolymer complexes of poly(acrylic acid) with poly(2-hydroxyethyl acrylate) in aqueous solutions

Vitaliy Khutoryanskiy; Grigoriy A. Mun; Vitaliy V. Khutoryanskiy; Gulnara T. Akhmetkalieva; Sergey N. Shmakov; Artem V. Dubolazov; Zauresh S. Nurkeeva; Kinam Park

doi:10.1007/s00396-004-1115-2

Interpolymer complexes of poly(acrylic acid) with poly(2-hydroxyethyl acrylate) in aqueous solutions

Vitaliy Khutoryanskiy, Grigoriy A. Mun, Vitaliy V. Khutoryanskiy, Gulnara T. Akhmetkalieva, Sergey N. Shmakov, Artem V. Dubolazov, Zauresh S. Nurkeeva, Kinam Park

Research output: Contribution to journal › Article › peer-review

Abstract

Complexes formed from poly(acrylic acid) and poly(2-hydroxyethyl acrylate) were studied in aqueous solutions by viscometric, turbidimetric, FTIR spectroscopic, and thermogravimetric analysis methods. The formation of interpolymer complexes stabilized by hydrogen bonds was observed. It was found that the compositions of these interpolymer complexes are strongly dependent on the concentration of polymers, the order of mixing the solutions, and the pH. It was demonstrated that the complexation ability of poly(2-hydroxyethyl acrylate) is relatively low compared to other known nonionic water-soluble polymers. However, it can be significantly increased via hydrophobic modification of the poly(acrylic acid) using cetyl pyridinium bromide. © Springer-Verlag 2004.

Original language	English
Pages (from-to)	174-181
Number of pages	7
Journal	Colloid and Polymer Science
Volume	283
Issue number	2
DOIs	https://doi.org/10.1007/s00396-004-1115-2
Publication status	Published - 2004

Keywords

Critical phenomena
Hydrogen bonding
Interpolymer complexes
Poly(2-hydroxyethyl acrylate)

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10.1007/s00396-004-1115-2

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title = "Interpolymer complexes of poly(acrylic acid) with poly(2-hydroxyethyl acrylate) in aqueous solutions",

abstract = "Complexes formed from poly(acrylic acid) and poly(2-hydroxyethyl acrylate) were studied in aqueous solutions by viscometric, turbidimetric, FTIR spectroscopic, and thermogravimetric analysis methods. The formation of interpolymer complexes stabilized by hydrogen bonds was observed. It was found that the compositions of these interpolymer complexes are strongly dependent on the concentration of polymers, the order of mixing the solutions, and the pH. It was demonstrated that the complexation ability of poly(2-hydroxyethyl acrylate) is relatively low compared to other known nonionic water-soluble polymers. However, it can be significantly increased via hydrophobic modification of the poly(acrylic acid) using cetyl pyridinium bromide. {\textcopyright} Springer-Verlag 2004.",

keywords = "Critical phenomena, Hydrogen bonding, Interpolymer complexes, Poly(2-hydroxyethyl acrylate)",

author = "Vitaliy Khutoryanskiy and Mun, {Grigoriy A.} and Khutoryanskiy, {Vitaliy V.} and Akhmetkalieva, {Gulnara T.} and Shmakov, {Sergey N.} and Dubolazov, {Artem V.} and Nurkeeva, {Zauresh S.} and Kinam Park",

year = "2004",

doi = "10.1007/s00396-004-1115-2",

language = "English",

volume = "283",

pages = "174--181",

journal = "Colloid and Polymer Science",

issn = "1435-1536",

publisher = "Springer Nature",

number = "2",

}

TY - JOUR

T1 - Interpolymer complexes of poly(acrylic acid) with poly(2-hydroxyethyl acrylate) in aqueous solutions

AU - Khutoryanskiy, Vitaliy

AU - Mun, Grigoriy A.

AU - Khutoryanskiy, Vitaliy V.

AU - Akhmetkalieva, Gulnara T.

AU - Shmakov, Sergey N.

AU - Dubolazov, Artem V.

AU - Nurkeeva, Zauresh S.

AU - Park, Kinam

PY - 2004

Y1 - 2004

N2 - Complexes formed from poly(acrylic acid) and poly(2-hydroxyethyl acrylate) were studied in aqueous solutions by viscometric, turbidimetric, FTIR spectroscopic, and thermogravimetric analysis methods. The formation of interpolymer complexes stabilized by hydrogen bonds was observed. It was found that the compositions of these interpolymer complexes are strongly dependent on the concentration of polymers, the order of mixing the solutions, and the pH. It was demonstrated that the complexation ability of poly(2-hydroxyethyl acrylate) is relatively low compared to other known nonionic water-soluble polymers. However, it can be significantly increased via hydrophobic modification of the poly(acrylic acid) using cetyl pyridinium bromide. © Springer-Verlag 2004.

AB - Complexes formed from poly(acrylic acid) and poly(2-hydroxyethyl acrylate) were studied in aqueous solutions by viscometric, turbidimetric, FTIR spectroscopic, and thermogravimetric analysis methods. The formation of interpolymer complexes stabilized by hydrogen bonds was observed. It was found that the compositions of these interpolymer complexes are strongly dependent on the concentration of polymers, the order of mixing the solutions, and the pH. It was demonstrated that the complexation ability of poly(2-hydroxyethyl acrylate) is relatively low compared to other known nonionic water-soluble polymers. However, it can be significantly increased via hydrophobic modification of the poly(acrylic acid) using cetyl pyridinium bromide. © Springer-Verlag 2004.

KW - Critical phenomena

KW - Hydrogen bonding

KW - Interpolymer complexes

KW - Poly(2-hydroxyethyl acrylate)

U2 - 10.1007/s00396-004-1115-2

DO - 10.1007/s00396-004-1115-2

M3 - Article

SN - 1435-1536

VL - 283

SP - 174

EP - 181

JO - Colloid and Polymer Science

JF - Colloid and Polymer Science

IS - 2

ER -

Interpolymer complexes of poly(acrylic acid) with poly(2-hydroxyethyl acrylate) in aqueous solutions

Abstract

Keywords

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