Intramolecular metathesis versus Kharasch reactions using the Grubbs metathesis catalyst: Towards catalyst economy

James Faulkner; Chris D. Edlin; David Fengas; Ian Preece; Peter Quayle; Stuart N. Richards

doi:10.1016/j.tetlet.2005.02.060

Intramolecular metathesis versus Kharasch reactions using the Grubbs metathesis catalyst: Towards catalyst economy

James Faulkner, Chris D. Edlin, David Fengas, Ian Preece, Peter Quayle, Stuart N. Richards

Research output: Contribution to journal › Article › peer-review

Abstract

The first generation Grubbs catalyst can promote either ring closing metathesis (RCM) or atom transfer radical cyclisation reactions (ATRC) depending upon the reaction conditions employed. © 2005 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	2381-2385
Number of pages	4
Journal	Tetrahedron Letters
Volume	46
Issue number	14
DOIs	https://doi.org/10.1016/j.tetlet.2005.02.060
Publication status	Published - 4 Apr 2005

Keywords

ATRC
Competition
Cyclisation
Decomposition
Grubbs
Kharasch
Metathesis
RCM
Stability

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10.1016/j.tetlet.2005.02.060

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title = "Intramolecular metathesis versus Kharasch reactions using the Grubbs metathesis catalyst: Towards catalyst economy",

abstract = "The first generation Grubbs catalyst can promote either ring closing metathesis (RCM) or atom transfer radical cyclisation reactions (ATRC) depending upon the reaction conditions employed. {\textcopyright} 2005 Elsevier Ltd. All rights reserved.",

keywords = "ATRC, Competition, Cyclisation, Decomposition, Grubbs, Kharasch, Metathesis, RCM, Stability",

author = "James Faulkner and Edlin, {Chris D.} and David Fengas and Ian Preece and Peter Quayle and Richards, {Stuart N.}",

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T1 - Intramolecular metathesis versus Kharasch reactions using the Grubbs metathesis catalyst: Towards catalyst economy

AU - Faulkner, James

AU - Edlin, Chris D.

AU - Fengas, David

AU - Preece, Ian

AU - Quayle, Peter

AU - Richards, Stuart N.

PY - 2005/4/4

Y1 - 2005/4/4

N2 - The first generation Grubbs catalyst can promote either ring closing metathesis (RCM) or atom transfer radical cyclisation reactions (ATRC) depending upon the reaction conditions employed. © 2005 Elsevier Ltd. All rights reserved.

AB - The first generation Grubbs catalyst can promote either ring closing metathesis (RCM) or atom transfer radical cyclisation reactions (ATRC) depending upon the reaction conditions employed. © 2005 Elsevier Ltd. All rights reserved.

KW - ATRC

KW - Competition

KW - Cyclisation

KW - Decomposition

KW - Grubbs

KW - Kharasch

KW - Metathesis

KW - RCM

KW - Stability

U2 - 10.1016/j.tetlet.2005.02.060

DO - 10.1016/j.tetlet.2005.02.060

M3 - Article

SN - 1873-3581

VL - 46

SP - 2381

EP - 2385

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 14

ER -

Intramolecular metathesis versus Kharasch reactions using the Grubbs metathesis catalyst: Towards catalyst economy

Abstract

Keywords

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