Ionothermal synthesis and crystal structures of metal phosphate chains

David S. Wragg; Benjamin Le Ouay; Andrew M. Beale; Matthew G. O'Brien; Alexandra M Z Slawin; John E. Warren; Timothy J. Prior; Russell E. Morris

doi:10.1016/j.jssc.2010.05.002

Ionothermal synthesis and crystal structures of metal phosphate chains

David S. Wragg, Benjamin Le Ouay, Andrew M. Beale, Matthew G. O'Brien, Alexandra M Z Slawin, John E. Warren, Timothy J. Prior, Russell E. Morris

Research output: Contribution to journal › Article › peer-review

Abstract

We have prepared isostructural aluminium and gallium phosphate chains by ionothermal reactions in 1-ethyl-3-methylimidazolium bromide and 1-ethylpyridinium bromide under a variety of conditions. The chains can be prepared as pure phases or along with three dimensional framework phases. The chains are favoured at shorter heating times and the crystallinity can be improved by addition of transition metal acetates and amines which are not included in the final structure. The chain can be prepared with or without the presence of hydrofluoric acid. © 2010 Elsevier Inc. All rights reserved.

Original language	English
Pages (from-to)	1625-1631
Number of pages	6
Journal	Journal of Solid State Chemistry
Volume	183
Issue number	7
DOIs	https://doi.org/10.1016/j.jssc.2010.05.002
Publication status	Published - Jul 2010

Keywords

Chain
Crystal structure
Ionothermal synthesis
X-ray diffraction

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10.1016/j.jssc.2010.05.002

CCDC 683427: Experimental Crystal Structure Determination
Wragg, D. S. (Contributor), Le Ouay, B. (Contributor), Beale, A. M. (Contributor), O'Brien, M. (Contributor), Slawin, A. M. Z. (Contributor), Warren, J. (Contributor), Prior, T. J. (Contributor) & Morris, R. E. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2011
DOI: 10.5517/ccqy51v, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccqy51v&sid=DataCite
Dataset
CCDC 778175: Experimental Crystal Structure Determination
Wragg, D. S. (Contributor), Le Ouay, B. (Contributor), Beale, A. M. (Contributor), O'Brien, M. (Contributor), Slawin, A. M. Z. (Contributor), Warren, J. (Contributor), Prior, T. J. (Contributor) & Morris, R. E. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2011
DOI: 10.5517/ccv3rf3, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccv3rf3&sid=DataCite
Dataset
CCDC 722366: Experimental Crystal Structure Determination
Wragg, D. S. (Contributor), Le Ouay, B. (Contributor), Beale, A. M. (Contributor), O'Brien, M. (Contributor), Slawin, A. M. Z. (Contributor), Warren, J. (Contributor), Prior, T. J. (Contributor) & Morris, R. E. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2011
DOI: 10.5517/ccs7p4t, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccs7p4t&sid=DataCite
Dataset

Cite this

@article{bfcc328531c4462a80bc49ddfb7eb782,

title = "Ionothermal synthesis and crystal structures of metal phosphate chains",

abstract = "We have prepared isostructural aluminium and gallium phosphate chains by ionothermal reactions in 1-ethyl-3-methylimidazolium bromide and 1-ethylpyridinium bromide under a variety of conditions. The chains can be prepared as pure phases or along with three dimensional framework phases. The chains are favoured at shorter heating times and the crystallinity can be improved by addition of transition metal acetates and amines which are not included in the final structure. The chain can be prepared with or without the presence of hydrofluoric acid. {\textcopyright} 2010 Elsevier Inc. All rights reserved.",

keywords = "Chain, Crystal structure, Ionothermal synthesis, X-ray diffraction",

author = "Wragg, {David S.} and {Le Ouay}, Benjamin and Beale, {Andrew M.} and O'Brien, {Matthew G.} and Slawin, {Alexandra M Z} and Warren, {John E.} and Prior, {Timothy J.} and Morris, {Russell E.}",

note = "7",

year = "2010",

month = jul,

doi = "10.1016/j.jssc.2010.05.002",

language = "English",

volume = "183",

pages = "1625--1631",

journal = "Journal of Solid State Chemistry",

publisher = "Elsevier BV",

number = "7",

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TY - JOUR

T1 - Ionothermal synthesis and crystal structures of metal phosphate chains

AU - Wragg, David S.

AU - Le Ouay, Benjamin

AU - Beale, Andrew M.

AU - O'Brien, Matthew G.

AU - Slawin, Alexandra M Z

AU - Warren, John E.

AU - Prior, Timothy J.

AU - Morris, Russell E.

N1 - 7

PY - 2010/7

Y1 - 2010/7

N2 - We have prepared isostructural aluminium and gallium phosphate chains by ionothermal reactions in 1-ethyl-3-methylimidazolium bromide and 1-ethylpyridinium bromide under a variety of conditions. The chains can be prepared as pure phases or along with three dimensional framework phases. The chains are favoured at shorter heating times and the crystallinity can be improved by addition of transition metal acetates and amines which are not included in the final structure. The chain can be prepared with or without the presence of hydrofluoric acid. © 2010 Elsevier Inc. All rights reserved.

AB - We have prepared isostructural aluminium and gallium phosphate chains by ionothermal reactions in 1-ethyl-3-methylimidazolium bromide and 1-ethylpyridinium bromide under a variety of conditions. The chains can be prepared as pure phases or along with three dimensional framework phases. The chains are favoured at shorter heating times and the crystallinity can be improved by addition of transition metal acetates and amines which are not included in the final structure. The chain can be prepared with or without the presence of hydrofluoric acid. © 2010 Elsevier Inc. All rights reserved.

KW - Chain

KW - Crystal structure

KW - Ionothermal synthesis

KW - X-ray diffraction

U2 - 10.1016/j.jssc.2010.05.002

DO - 10.1016/j.jssc.2010.05.002

M3 - Article

VL - 183

SP - 1625

EP - 1631

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 7

ER -

Ionothermal synthesis and crystal structures of metal phosphate chains

Abstract

Keywords

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Datasets

CCDC 683427: Experimental Crystal Structure Determination

CCDC 778175: Experimental Crystal Structure Determination

CCDC 722366: Experimental Crystal Structure Determination

Cite this