Ionothermal synthesis of two novel metal organophosphonates

Peter J. Byrne; David S. Wragg; John E. Warren; Russell E. Morris

doi:10.1039/b813731e

Ionothermal synthesis of two novel metal organophosphonates

Peter J. Byrne, David S. Wragg, John E. Warren, Russell E. Morris

Research output: Contribution to journal › Article › peer-review

Abstract

Two novel metal phosphonates, Al5F(C4H 9PO3)6(OH)2(C4N 2H6)21 and Ga4F2(C 4H9PO3)8H5·(C 7N2H11) 2 have been prepared using an ionothermal approach and their structures solved using single-crystal X-ray diffraction. In 1, the breakdown of the ionic liquid solvent has occurred and a fragment of the cation coordinates to the aluminium in the structure. In 2, the ionic liquid cation acts as the template and is occluded. Compound 1 is a chain structure while compound 2 is molecular, unlike the vast majority of hydrothermally synthesised phosphonates, which are layered. © 2009 The Royal Society of Chemistry.

Original language	English
Pages (from-to)	795-799
Number of pages	4
Journal	Dalton Transactions
Issue number	5
DOIs	https://doi.org/10.1039/b813731e
Publication status	Published - 2009

Access to Document

10.1039/b813731e

CCDC 697759: Experimental Crystal Structure Determination
Byrne, P. J. (Contributor), Wragg, D. S. (Contributor), Warren, J. (Contributor) & Morris, R. E. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2009
DOI: 10.5517/ccrf2cl, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccrf2cl&sid=DataCite
Dataset
CCDC 697758: Experimental Crystal Structure Determination
Byrne, P. J. (Contributor), Wragg, D. S. (Contributor), Warren, J. (Contributor) & Morris, R. E. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2009
DOI: 10.5517/ccrf2bk, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccrf2bk&sid=DataCite
Dataset

Cite this

@article{8907818f38414f4a80a979523caa4497,

title = "Ionothermal synthesis of two novel metal organophosphonates",

abstract = "Two novel metal phosphonates, Al5F(C4H 9PO3)6(OH)2(C4N 2H6)21 and Ga4F2(C 4H9PO3)8H5·(C 7N2H11) 2 have been prepared using an ionothermal approach and their structures solved using single-crystal X-ray diffraction. In 1, the breakdown of the ionic liquid solvent has occurred and a fragment of the cation coordinates to the aluminium in the structure. In 2, the ionic liquid cation acts as the template and is occluded. Compound 1 is a chain structure while compound 2 is molecular, unlike the vast majority of hydrothermally synthesised phosphonates, which are layered. {\textcopyright} 2009 The Royal Society of Chemistry.",

author = "Byrne, {Peter J.} and Wragg, {David S.} and Warren, {John E.} and Morris, {Russell E.}",

note = "5",

year = "2009",

doi = "10.1039/b813731e",

language = "English",

pages = "795--799",

journal = "Dalton Transactions",

issn = "1477-9234",

publisher = "Royal Society of Chemistry",

number = "5",

}

TY - JOUR

T1 - Ionothermal synthesis of two novel metal organophosphonates

AU - Byrne, Peter J.

AU - Wragg, David S.

AU - Warren, John E.

AU - Morris, Russell E.

N1 - 5

PY - 2009

Y1 - 2009

N2 - Two novel metal phosphonates, Al5F(C4H 9PO3)6(OH)2(C4N 2H6)21 and Ga4F2(C 4H9PO3)8H5·(C 7N2H11) 2 have been prepared using an ionothermal approach and their structures solved using single-crystal X-ray diffraction. In 1, the breakdown of the ionic liquid solvent has occurred and a fragment of the cation coordinates to the aluminium in the structure. In 2, the ionic liquid cation acts as the template and is occluded. Compound 1 is a chain structure while compound 2 is molecular, unlike the vast majority of hydrothermally synthesised phosphonates, which are layered. © 2009 The Royal Society of Chemistry.

AB - Two novel metal phosphonates, Al5F(C4H 9PO3)6(OH)2(C4N 2H6)21 and Ga4F2(C 4H9PO3)8H5·(C 7N2H11) 2 have been prepared using an ionothermal approach and their structures solved using single-crystal X-ray diffraction. In 1, the breakdown of the ionic liquid solvent has occurred and a fragment of the cation coordinates to the aluminium in the structure. In 2, the ionic liquid cation acts as the template and is occluded. Compound 1 is a chain structure while compound 2 is molecular, unlike the vast majority of hydrothermally synthesised phosphonates, which are layered. © 2009 The Royal Society of Chemistry.

U2 - 10.1039/b813731e

DO - 10.1039/b813731e

M3 - Article

SN - 1477-9234

SP - 795

EP - 799

JO - Dalton Transactions

JF - Dalton Transactions

IS - 5

ER -

Ionothermal synthesis of two novel metal organophosphonates

Abstract

Access to Document

Fingerprint

Datasets

CCDC 697759: Experimental Crystal Structure Determination

CCDC 697758: Experimental Crystal Structure Determination

Cite this