Iron and porphyrin metal-organic frameworks: Insight into structural diversity, stability, and porosity

Alexandra Fateeva; Jade Clarisse; Guillaume Pilet; Jean Marc Grenèche; Farid Nouar; Brian K. Abeykoon; Frédéric Guegan; Christelle Goutaudier; Dominique Luneau; John E. Warren; Matthew J. Rosseinsky; Thomas Devic

doi:10.1021/cg501855k

Iron and porphyrin metal-organic frameworks: Insight into structural diversity, stability, and porosity

Alexandra Fateeva^*, Jade Clarisse, Guillaume Pilet, Jean Marc Grenèche, Farid Nouar, Brian K. Abeykoon, Frédéric Guegan, Christelle Goutaudier, Dominique Luneau, John E. Warren, Matthew J. Rosseinsky, Thomas Devic

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of iron(IIII)chloride with the free base tetrakis(4-carboxyphenyl)porphyrin (H₂TCPP) in the presence of different bases leads to the formation of a series of iron/porphyrin metal-organic frameworks. Such a crystal engineering approach led to the obtaining of four structures presenting three different topologies and inorganic secondary building units. Depending on the synthesis conditions, isolated Fe^III octahedra, diiron(II) paddle wheel dimers, or extended [Fe^III(OH)O₄]_n chains could be obtained in a controlled manner. The influence of the synthetic conditions on the final structure and the oxidation state of iron is discussed. Stability of the porous solids towards air and water is studied, and their intrinsic porosity is assessed.

Original language	English
Pages (from-to)	1819-1826
Number of pages	8
Journal	Crystal Growth and Design
Volume	15
Issue number	4
DOIs	https://doi.org/10.1021/cg501855k
Publication status	Published - 1 Apr 2015
Externally published	Yes

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10.1021/cg501855k

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title = "Iron and porphyrin metal-organic frameworks: Insight into structural diversity, stability, and porosity",

abstract = "Reaction of iron(IIII)chloride with the free base tetrakis(4-carboxyphenyl)porphyrin (H2TCPP) in the presence of different bases leads to the formation of a series of iron/porphyrin metal-organic frameworks. Such a crystal engineering approach led to the obtaining of four structures presenting three different topologies and inorganic secondary building units. Depending on the synthesis conditions, isolated FeIII octahedra, diiron(II) paddle wheel dimers, or extended [FeIII(OH)O4]n chains could be obtained in a controlled manner. The influence of the synthetic conditions on the final structure and the oxidation state of iron is discussed. Stability of the porous solids towards air and water is studied, and their intrinsic porosity is assessed.",

author = "Alexandra Fateeva and Jade Clarisse and Guillaume Pilet and Gren{\`e}che, {Jean Marc} and Farid Nouar and Abeykoon, {Brian K.} and Fr{\'e}d{\'e}ric Guegan and Christelle Goutaudier and Dominique Luneau and Warren, {John E.} and Rosseinsky, {Matthew J.} and Thomas Devic",

year = "2015",

month = apr,

day = "1",

doi = "10.1021/cg501855k",

language = "English",

volume = "15",

pages = "1819--1826",

journal = "Crystal Growth and Design",

issn = "1528-7483",

publisher = "American Chemical Society",

number = "4",

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TY - JOUR

T1 - Iron and porphyrin metal-organic frameworks

T2 - Insight into structural diversity, stability, and porosity

AU - Fateeva, Alexandra

AU - Clarisse, Jade

AU - Pilet, Guillaume

AU - Grenèche, Jean Marc

AU - Nouar, Farid

AU - Abeykoon, Brian K.

AU - Guegan, Frédéric

AU - Goutaudier, Christelle

AU - Luneau, Dominique

AU - Warren, John E.

AU - Rosseinsky, Matthew J.

AU - Devic, Thomas

PY - 2015/4/1

Y1 - 2015/4/1

N2 - Reaction of iron(IIII)chloride with the free base tetrakis(4-carboxyphenyl)porphyrin (H2TCPP) in the presence of different bases leads to the formation of a series of iron/porphyrin metal-organic frameworks. Such a crystal engineering approach led to the obtaining of four structures presenting three different topologies and inorganic secondary building units. Depending on the synthesis conditions, isolated FeIII octahedra, diiron(II) paddle wheel dimers, or extended [FeIII(OH)O4]n chains could be obtained in a controlled manner. The influence of the synthetic conditions on the final structure and the oxidation state of iron is discussed. Stability of the porous solids towards air and water is studied, and their intrinsic porosity is assessed.

AB - Reaction of iron(IIII)chloride with the free base tetrakis(4-carboxyphenyl)porphyrin (H2TCPP) in the presence of different bases leads to the formation of a series of iron/porphyrin metal-organic frameworks. Such a crystal engineering approach led to the obtaining of four structures presenting three different topologies and inorganic secondary building units. Depending on the synthesis conditions, isolated FeIII octahedra, diiron(II) paddle wheel dimers, or extended [FeIII(OH)O4]n chains could be obtained in a controlled manner. The influence of the synthetic conditions on the final structure and the oxidation state of iron is discussed. Stability of the porous solids towards air and water is studied, and their intrinsic porosity is assessed.

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U2 - 10.1021/cg501855k

DO - 10.1021/cg501855k

M3 - Article

AN - SCOPUS:84926352946

SN - 1528-7483

VL - 15

SP - 1819

EP - 1826

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 4

ER -

Iron and porphyrin metal-organic frameworks: Insight into structural diversity, stability, and porosity

Abstract

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CCDC 1031514: Experimental Crystal Structure Determination

CCDC 1031515: Experimental Crystal Structure Determination

CCDC 1031418: Experimental Crystal Structure Determination

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Iron and porphyrin metal-organic frameworks: Insight into structural diversity, stability, and porosity

Abstract

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Datasets

CCDC 1031514: Experimental Crystal Structure Determination

CCDC 1031515: Experimental Crystal Structure Determination

CCDC 1031418: Experimental Crystal Structure Determination

Cite this