Isolated PdO sites on SiO2-supported NiO nanoparticles as active sites for allylic alcohol selective oxidation

Aleksandra Ziarko; Thomas J. A. Slater; Mark A. Isaacs; Lee J. Durndell; Christopher M. A. Parlett

doi:10.1039/d3cy00198a

Isolated PdO sites on SiO2-supported NiO nanoparticles as active sites for allylic alcohol selective oxidation

Aleksandra Ziarko, Thomas J. A. Slater, Mark A. Isaacs, Lee J. Durndell, Christopher M. A. Parlett

CE - Academic & Research

Research output: Contribution to journal › Article › peer-review

Abstract

Catalytic allylic alcohol oxidation to aldehydes is an industrial process that necessitates chemoselectivity. Surface PdO (on Pd) enables this transformation but does not represent optimal metal utilisation. Here we report a facile synthesis route to produce isolated surface PdO catalytic sites on an earth-abundant metal (NiO) for cinnamyl alcohol oxidation.

Original language	English
Pages (from-to)	3483-3488
Number of pages	6
Journal	Catalysis Science & Technology
Volume	13
Issue number	12
Early online date	12 May 2023
DOIs	https://doi.org/10.1039/d3cy00198a
Publication status	Published - 21 Jun 2023

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10.1039/d3cy00198aLicence: CC BY

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abstract = "Catalytic allylic alcohol oxidation to aldehydes is an industrial process that necessitates chemoselectivity. Surface PdO (on Pd) enables this transformation but does not represent optimal metal utilisation. Here we report a facile synthesis route to produce isolated surface PdO catalytic sites on an earth-abundant metal (NiO) for cinnamyl alcohol oxidation.",

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AU - Parlett, Christopher M. A.

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Isolated PdO sites on SiO2-supported NiO nanoparticles as active sites for allylic alcohol selective oxidation

Abstract

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UoMaH: The University of Manchester at Harwell

XAS dataset for NiO@PdO/SiO2 Pd k edge and Ni k edge ex-situ and Pd k edge operando study

Cinnamyl alcohol selective oxidation over NiO@PdO/SiO2