Isothermal annealing behaviour of nuclear grade 20Cr-25Ni austenitic stainless steel

We have performed an in-depth characterisation of the microstructure evolution of 20Cr-25Ni Nb-stabilised austenitic stainless steel during isothermal annealing at 930C using scanning and transmission electron microscopy. This steel grade is used as cladding material in advanced gas-cooled fission reactors, due to its resistance to thermal creep and water corrosion. The initial deformed microstructure undergoes recrystallization via a strain-induced boundary migration mechanism, attaining a fully recrystallized microstructure after 120s of annealing. The transition from low-to-high grain boundaries has already occurred after 15s, together with an increase in the cube grain orientation at the expense of the S texture component. After 120s, the grain boundary migration induces the formation of new fine Nb(C,N) particles, whereas the pre-existing particles become enriched in Ni and Si. The resulting particle population limits the grain growth in the austenitic matrix, based on the Zener pinning model, resulting in relatively small recrystallized austenite grains and a high density of high-angle and special coincidence-lattice-site grain boundaries, together with a large number of particle/matrix interfaces.