Kinetics of the reaction of CH3Ch + NO: A temperature and pressure dependence study with chemical ionization mass spectrometry

Asan Bacak, Max W. Bardwell, M. Teresa Raventos, Carl J. Percival, Gabriela Sanchez-Reyna, Dudley E. Shallcross

    Research output: Contribution to journalArticlepeer-review

    Abstract

    The overall rate coefficient for the reaction CH3O2 + NO → products was measured by using the turbulent flow technique with chemical ionization mass spectrometry (CIMS). The temperature dependence of the rate coefficient between 193 and 300 K was investigated. A model of the troposphere was used to assess the impact of the experimental error of the rate coefficients. It was found that the propogated error was very small, and was not a major cause of uncertainty in modeled concentrations.
    Original languageEnglish
    Pages (from-to)10681-10687
    Number of pages6
    JournalJournal of Physical Chemistry A
    Volume108
    Issue number48
    DOIs
    Publication statusPublished - 2 Dec 2004

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