Kinetics of the reaction of CH3Ch + NO: A temperature and pressure dependence study with chemical ionization mass spectrometry

Asan Bacak; Max W. Bardwell; M. Teresa Raventos; Carl J. Percival; Gabriela Sanchez-Reyna; Dudley E. Shallcross

doi:10.1021/jp047764b

Kinetics of the reaction of CH3Ch + NO: A temperature and pressure dependence study with chemical ionization mass spectrometry

Asan Bacak, Max W. Bardwell, M. Teresa Raventos, Carl J. Percival, Gabriela Sanchez-Reyna, Dudley E. Shallcross

Research output: Contribution to journal › Article › peer-review

Abstract

The overall rate coefficient for the reaction CH3O2 + NO → products was measured by using the turbulent flow technique with chemical ionization mass spectrometry (CIMS). The temperature dependence of the rate coefficient between 193 and 300 K was investigated. A model of the troposphere was used to assess the impact of the experimental error of the rate coefficients. It was found that the propogated error was very small, and was not a major cause of uncertainty in modeled concentrations.

Original language	English
Pages (from-to)	10681-10687
Number of pages	6
Journal	Journal of Physical Chemistry A
Volume	108
Issue number	48
DOIs	https://doi.org/10.1021/jp047764b
Publication status	Published - 2 Dec 2004

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title = "Kinetics of the reaction of CH3Ch + NO: A temperature and pressure dependence study with chemical ionization mass spectrometry",

abstract = "The overall rate coefficient for the reaction CH3O2 + NO → products was measured by using the turbulent flow technique with chemical ionization mass spectrometry (CIMS). The temperature dependence of the rate coefficient between 193 and 300 K was investigated. A model of the troposphere was used to assess the impact of the experimental error of the rate coefficients. It was found that the propogated error was very small, and was not a major cause of uncertainty in modeled concentrations.",

author = "Asan Bacak and Bardwell, {Max W.} and Raventos, {M. Teresa} and Percival, {Carl J.} and Gabriela Sanchez-Reyna and Shallcross, {Dudley E.}",

year = "2004",

month = dec,

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doi = "10.1021/jp047764b",

language = "English",

volume = "108",

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T1 - Kinetics of the reaction of CH3Ch + NO: A temperature and pressure dependence study with chemical ionization mass spectrometry

AU - Bacak, Asan

AU - Bardwell, Max W.

AU - Raventos, M. Teresa

AU - Percival, Carl J.

AU - Sanchez-Reyna, Gabriela

AU - Shallcross, Dudley E.

PY - 2004/12/2

Y1 - 2004/12/2

N2 - The overall rate coefficient for the reaction CH3O2 + NO → products was measured by using the turbulent flow technique with chemical ionization mass spectrometry (CIMS). The temperature dependence of the rate coefficient between 193 and 300 K was investigated. A model of the troposphere was used to assess the impact of the experimental error of the rate coefficients. It was found that the propogated error was very small, and was not a major cause of uncertainty in modeled concentrations.

AB - The overall rate coefficient for the reaction CH3O2 + NO → products was measured by using the turbulent flow technique with chemical ionization mass spectrometry (CIMS). The temperature dependence of the rate coefficient between 193 and 300 K was investigated. A model of the troposphere was used to assess the impact of the experimental error of the rate coefficients. It was found that the propogated error was very small, and was not a major cause of uncertainty in modeled concentrations.

U2 - 10.1021/jp047764b

DO - 10.1021/jp047764b

M3 - Article

VL - 108

SP - 10681

EP - 10687

JO - The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory

JF - The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory

SN - 1089-5639

IS - 48

ER -

Kinetics of the reaction of CH3Ch + NO: A temperature and pressure dependence study with chemical ionization mass spectrometry

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