Lanthanide complexes of DOTA monoamide derivatives bearing an isophthalate pendent arm

Emma J. Shiells; Louise S. Natrajan; Daniel Sykes; Manuel Tropiano; Paul Cooper; Alan M. Kenwright; Stephen Faulkner

doi:10.1039/c1dt11029b

Lanthanide complexes of DOTA monoamide derivatives bearing an isophthalate pendent arm

Emma J. Shiells, Louise S. Natrajan, Daniel Sykes, Manuel Tropiano, Paul Cooper, Alan M. Kenwright, Stephen Faulkner

Research output: Contribution to journal › Article › peer-review

Abstract

An isophthalate-bearing DOTA monoamide derivative has been synthesised and used to prepare a family of lanthanide complexes. Luminescence and NMR studies in solution show that the predominant form of the complexes in solution is a mono-capped square antiprism about the lanthanide centre, in which a solvent molecule occupies the ninth coordination site. The crystal structure of the terbium complex is presented and is in close agreement with the solution state data. © 2011 The Royal Society of Chemistry.

Original language	English
Pages (from-to)	11451-11457
Number of pages	6
Journal	Dalton Transactions
Volume	40
Issue number	43
DOIs	https://doi.org/10.1039/c1dt11029b
Publication status	Published - 21 Nov 2011

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10.1039/c1dt11029b

CCDC 828726: Experimental Crystal Structure Determination
Shiells, E. J. (Contributor), Natrajan, L. (Contributor), Sykes, D. (Contributor), Tropiano, M. (Contributor), Cooper, P. (Contributor), Kenwright, A. M. (Contributor) & Faulkner, S. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2012
DOI: 10.5517/ccwtc34, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccwtc34&sid=DataCite
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abstract = "An isophthalate-bearing DOTA monoamide derivative has been synthesised and used to prepare a family of lanthanide complexes. Luminescence and NMR studies in solution show that the predominant form of the complexes in solution is a mono-capped square antiprism about the lanthanide centre, in which a solvent molecule occupies the ninth coordination site. The crystal structure of the terbium complex is presented and is in close agreement with the solution state data. {\textcopyright} 2011 The Royal Society of Chemistry.",

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AU - Shiells, Emma J.

AU - Natrajan, Louise S.

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AU - Cooper, Paul

AU - Kenwright, Alan M.

AU - Faulkner, Stephen

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AB - An isophthalate-bearing DOTA monoamide derivative has been synthesised and used to prepare a family of lanthanide complexes. Luminescence and NMR studies in solution show that the predominant form of the complexes in solution is a mono-capped square antiprism about the lanthanide centre, in which a solvent molecule occupies the ninth coordination site. The crystal structure of the terbium complex is presented and is in close agreement with the solution state data. © 2011 The Royal Society of Chemistry.

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DO - 10.1039/c1dt11029b

M3 - Article

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VL - 40

SP - 11451

EP - 11457

JO - Dalton Transactions

JF - Dalton Transactions

IS - 43

ER -

Lanthanide complexes of DOTA monoamide derivatives bearing an isophthalate pendent arm

Abstract

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Datasets

CCDC 828726: Experimental Crystal Structure Determination

Cite this