Lanthanide crown ether complexes of p-sulfonatocalix[5]arene

Scott J. Dalgarno; Michaele J. Hardie; John E. Warren; Colin L. Raston

doi:10.1039/b407207c

Lanthanide crown ether complexes of p-sulfonatocalix[5]arene

Scott J. Dalgarno, Michaele J. Hardie, John E. Warren, Colin L. Raston

Research output: Contribution to journal › Article › peer-review

Abstract

Two types of arrays are formed in water involving aza-crown ethers, p-sulfonatocalix[5]arene and europium(III) ions. One is a co-ordination polymer connecting calixarenes, sodium ions and lanthanide ions based on 'ferris wheel' moieties incorporating aza-18-crown-6 and sodium ions. The second structure is a host-guest arrangement with di-protonated diaza-18-crown-6 in the cavity of the calixarenes as part of secondary coordination spheres of aquated europium(III) ions.

Original language	English
Pages (from-to)	2413-2416
Number of pages	3
Journal	Dalton Transactions
Issue number	16
DOIs	https://doi.org/10.1039/b407207c
Publication status	Published - 21 Aug 2004

Keywords

{ASSEMBLIES
{CALIXARENES
CHEMISTRY
CONFINEMENT
{CONFINEMENT
CONFORMATION
{CONFORMATION
COORDINATION
IONS
{IONS
POLYMERS
{POLYMERS
SOLID-STATE
WATER
} P-{SULFONATOCALIX{\textless}4{\textgreater}ARENE
P-{SULFONATOCALIX{\textless}4{\textgreater}ARENE}
P-{SULFONATOCALIX{\textless}4{\textgreater}ARENE
{SOLID-STATE
SULFONATED
SULFONATED} {CALIXARENES
SUPRAMOLECULAR
SUPRAMOLECULAR} {ASSEMBLIES
{SUPRAMOLECULAR} {ASSEMBLIES
SULFONATED CALIXARENES
{WATER

Access to Document

10.1039/b407207c

CCDC 238599: Experimental Crystal Structure Determination
Dalgarno, S. J. (Contributor), Hardie, M. J. (Contributor), Warren, J. (Contributor) & Raston, C. L. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2005
DOI: 10.5517/cc808r8, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc808r8&sid=DataCite
Dataset
CCDC 238600: Experimental Crystal Structure Determination
Dalgarno, S. J. (Contributor), Hardie, M. J. (Contributor), Warren, J. (Contributor) & Raston, C. L. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2005
DOI: 10.5517/cc808s9, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc808s9&sid=DataCite
Dataset

Cite this

@article{6c637286ab09428d99455e3dbfb8c0e5,

title = "Lanthanide crown ether complexes of p-sulfonatocalix[5]arene",

abstract = "Two types of arrays are formed in water involving aza-crown ethers, p-sulfonatocalix[5]arene and europium(III) ions. One is a co-ordination polymer connecting calixarenes, sodium ions and lanthanide ions based on 'ferris wheel' moieties incorporating aza-18-crown-6 and sodium ions. The second structure is a host-guest arrangement with di-protonated diaza-18-crown-6 in the cavity of the calixarenes as part of secondary coordination spheres of aquated europium(III) ions.",

keywords = "{ASSEMBLIES, {CALIXARENES, CHEMISTRY, CONFINEMENT, {CONFINEMENT, CONFORMATION, {CONFORMATION, COORDINATION, IONS, {IONS, POLYMERS, {POLYMERS, SOLID-STATE, WATER, } P-{SULFONATOCALIX{\textless}4{\textgreater}ARENE, P-{SULFONATOCALIX{\textless}4{\textgreater}ARENE}, P-{SULFONATOCALIX{\textless}4{\textgreater}ARENE, {SOLID-STATE, SULFONATED, SULFONATED} {CALIXARENES, SUPRAMOLECULAR, SUPRAMOLECULAR} {ASSEMBLIES, {SUPRAMOLECULAR} {ASSEMBLIES, SULFONATED CALIXARENES, {WATER",

author = "Dalgarno, {Scott J.} and Hardie, {Michaele J.} and Warren, {John E.} and Raston, {Colin L.}",

note = "16",

year = "2004",

month = aug,

day = "21",

doi = "10.1039/b407207c",

language = "English",

pages = "2413--2416",

journal = "Dalton Transactions",

issn = "1477-9234",

publisher = "Royal Society of Chemistry",

number = "16",

}

TY - JOUR

T1 - Lanthanide crown ether complexes of p-sulfonatocalix[5]arene

AU - Dalgarno, Scott J.

AU - Hardie, Michaele J.

AU - Warren, John E.

AU - Raston, Colin L.

N1 - 16

PY - 2004/8/21

Y1 - 2004/8/21

N2 - Two types of arrays are formed in water involving aza-crown ethers, p-sulfonatocalix[5]arene and europium(III) ions. One is a co-ordination polymer connecting calixarenes, sodium ions and lanthanide ions based on 'ferris wheel' moieties incorporating aza-18-crown-6 and sodium ions. The second structure is a host-guest arrangement with di-protonated diaza-18-crown-6 in the cavity of the calixarenes as part of secondary coordination spheres of aquated europium(III) ions.

AB - Two types of arrays are formed in water involving aza-crown ethers, p-sulfonatocalix[5]arene and europium(III) ions. One is a co-ordination polymer connecting calixarenes, sodium ions and lanthanide ions based on 'ferris wheel' moieties incorporating aza-18-crown-6 and sodium ions. The second structure is a host-guest arrangement with di-protonated diaza-18-crown-6 in the cavity of the calixarenes as part of secondary coordination spheres of aquated europium(III) ions.

KW - {ASSEMBLIES

KW - {CALIXARENES

KW - CHEMISTRY

KW - CONFINEMENT

KW - {CONFINEMENT

KW - CONFORMATION

KW - {CONFORMATION

KW - COORDINATION

KW - IONS

KW - {IONS

KW - POLYMERS

KW - {POLYMERS

KW - SOLID-STATE

KW - WATER

KW - } P-{SULFONATOCALIX{\textless}4{\textgreater}ARENE

KW - P-{SULFONATOCALIX{\textless}4{\textgreater}ARENE}

KW - P-{SULFONATOCALIX{\textless}4{\textgreater}ARENE

KW - {SOLID-STATE

KW - SULFONATED

KW - SULFONATED} {CALIXARENES

KW - SUPRAMOLECULAR

KW - SUPRAMOLECULAR} {ASSEMBLIES

KW - {SUPRAMOLECULAR} {ASSEMBLIES

KW - SULFONATED CALIXARENES

KW - {WATER

U2 - 10.1039/b407207c

DO - 10.1039/b407207c

M3 - Article

SN - 1477-9234

SP - 2413

EP - 2416

JO - Dalton Transactions

JF - Dalton Transactions

IS - 16

ER -

Lanthanide crown ether complexes of p-sulfonatocalix[5]arene

Abstract

Keywords

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Datasets

CCDC 238599: Experimental Crystal Structure Determination

CCDC 238600: Experimental Crystal Structure Determination

Cite this