Mössbauer study of pyrrhotite

D. J. Vaughan; M. S. Ridout

doi:10.1016/0038-1098(70)90242-5

Mössbauer study of pyrrhotite

D. J. Vaughan^*, M. S. Ridout

^*Corresponding author for this work

Earth and Environmental Sciences - Academic & Research

Atomic Energy Research Establishment

Research output: Contribution to journal › Article › peer-review

Abstract

Mössbauer spectra of natural monoclinic pyrrhotite (Fe₇S₈) have been determined at 300, 77 and 4.2°K and interpreted using a least squares fit computer programme. The spectrum at 77°K was resolved into five components. Four have a finite hyperfine field and one has zero hyperfine field gradient. The parameters obtained from the fit agree with the model of vacancy ordering in Fe₇S₈ proposed by Bertaut.

Original language	English
Pages (from-to)	2165-2167
Number of pages	3
Journal	Solid State Communications
Volume	8
Issue number	24
DOIs	https://doi.org/10.1016/0038-1098(70)90242-5
Publication status	Published - 15 Dec 1970

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title = "M{\"o}ssbauer study of pyrrhotite",

abstract = "M{\"o}ssbauer spectra of natural monoclinic pyrrhotite (Fe7S8) have been determined at 300, 77 and 4.2°K and interpreted using a least squares fit computer programme. The spectrum at 77°K was resolved into five components. Four have a finite hyperfine field and one has zero hyperfine field gradient. The parameters obtained from the fit agree with the model of vacancy ordering in Fe7S8 proposed by Bertaut.",

author = "Vaughan, {D. J.} and Ridout, {M. S.}",

note = "Funding Information: Acknowledgements — D.J. Vaughan acknowledges the financial support of the Natural Environment Research Council.",

year = "1970",

month = dec,

day = "15",

doi = "10.1016/0038-1098(70)90242-5",

language = "English",

volume = "8",

pages = "2165--2167",

journal = "Solid State Communications",

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number = "24",

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T1 - Mössbauer study of pyrrhotite

AU - Vaughan, D. J.

AU - Ridout, M. S.

N1 - Funding Information: Acknowledgements — D.J. Vaughan acknowledges the financial support of the Natural Environment Research Council.

PY - 1970/12/15

Y1 - 1970/12/15

N2 - Mössbauer spectra of natural monoclinic pyrrhotite (Fe7S8) have been determined at 300, 77 and 4.2°K and interpreted using a least squares fit computer programme. The spectrum at 77°K was resolved into five components. Four have a finite hyperfine field and one has zero hyperfine field gradient. The parameters obtained from the fit agree with the model of vacancy ordering in Fe7S8 proposed by Bertaut.

AB - Mössbauer spectra of natural monoclinic pyrrhotite (Fe7S8) have been determined at 300, 77 and 4.2°K and interpreted using a least squares fit computer programme. The spectrum at 77°K was resolved into five components. Four have a finite hyperfine field and one has zero hyperfine field gradient. The parameters obtained from the fit agree with the model of vacancy ordering in Fe7S8 proposed by Bertaut.

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U2 - 10.1016/0038-1098(70)90242-5

DO - 10.1016/0038-1098(70)90242-5

M3 - Article

AN - SCOPUS:0014928286

SN - 0038-1098

VL - 8

SP - 2165

EP - 2167

JO - Solid State Communications

JF - Solid State Communications

IS - 24

ER -

Mössbauer study of pyrrhotite

Abstract

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