Macrocyclic sulfamides: synthesis, hybridization, and metal binding properties

Patrick D. Bailey; Anuparma Sethi; Robin G. Pritchard

doi:10.1016/j.tetlet.2008.01.087

Macrocyclic sulfamides: synthesis, hybridization, and metal binding properties

Patrick D. Bailey
, Anuparma Sethi
, Robin G. Pritchard

Research output: Contribution to journal › Article › peer-review

Abstract

Four cyclophanes incorporating the cyclosulfamide sub-unit have been synthesised in high yield. The X-ray crystal structures of three of them, and of cyclosulfamide itself, provide useful insight into the hybridisation of such compounds. The ionophoric properties of the macrocycles are also reported, with the sulfamides showing unusual selectivity for rubidium (benzyl trimer), barium (pyridyl dimer) and silver (pyridyl dimer and trimer). © 2008 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	2159-2162
Number of pages	3
Journal	Tetrahedron Letters
Volume	49
Issue number	13
DOIs	https://doi.org/10.1016/j.tetlet.2008.01.087
Publication status	Published - 24 Mar 2008

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10.1016/j.tetlet.2008.01.087

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abstract = "Four cyclophanes incorporating the cyclosulfamide sub-unit have been synthesised in high yield. The X-ray crystal structures of three of them, and of cyclosulfamide itself, provide useful insight into the hybridisation of such compounds. The ionophoric properties of the macrocycles are also reported, with the sulfamides showing unusual selectivity for rubidium (benzyl trimer), barium (pyridyl dimer) and silver (pyridyl dimer and trimer). {\textcopyright} 2008 Elsevier Ltd. All rights reserved.",

author = "Bailey, \{Patrick D.\} and Anuparma Sethi and Pritchard, \{Robin G.\}",

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AU - Sethi, Anuparma

AU - Pritchard, Robin G.

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N2 - Four cyclophanes incorporating the cyclosulfamide sub-unit have been synthesised in high yield. The X-ray crystal structures of three of them, and of cyclosulfamide itself, provide useful insight into the hybridisation of such compounds. The ionophoric properties of the macrocycles are also reported, with the sulfamides showing unusual selectivity for rubidium (benzyl trimer), barium (pyridyl dimer) and silver (pyridyl dimer and trimer). © 2008 Elsevier Ltd. All rights reserved.

AB - Four cyclophanes incorporating the cyclosulfamide sub-unit have been synthesised in high yield. The X-ray crystal structures of three of them, and of cyclosulfamide itself, provide useful insight into the hybridisation of such compounds. The ionophoric properties of the macrocycles are also reported, with the sulfamides showing unusual selectivity for rubidium (benzyl trimer), barium (pyridyl dimer) and silver (pyridyl dimer and trimer). © 2008 Elsevier Ltd. All rights reserved.

UR - https://www.ccdc.cam.ac.uk/structures/search?id=doi:10.5517/ccqqv6g&sid=DataCite

U2 - 10.1016/j.tetlet.2008.01.087

DO - 10.1016/j.tetlet.2008.01.087

M3 - Article

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VL - 49

SP - 2159

EP - 2162

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 13

ER -

Macrocyclic sulfamides: synthesis, hybridization, and metal binding properties

Abstract

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