Macrocyclic thioether complexes of palladium with dibromoiodide anions

Martin Schroder, A J Blake, M Schröder, L M Gilby, R O Gould, V Lippolis, S Parsons

    Research output: Contribution to journalArticlepeer-review

    Abstract

    The structure of bis(1,4,7-trithiacyclononane)palladium(II) bis(dibromoiodide), [Pd(C6H12S3)2](IBr2)2 comprises ribbons in which neighbouring cations are linked by pairs of anions through S...Br contacts of 3.767 (5)-3.877 (5) Å. In (1,4,8,11-tetrathiacyclotetradecane)palladium(II) bis(dibromoiodide), [Pd(C10H20S4)2](IBr2)2, Pd...I, S...Br and S...I contacts link cations and anions into an infinite three-dimensional network.
    Original languageEnglish
    Pages (from-to)295-298
    Number of pages4
    JournalActa Crystallographica. Section C: Structural Chemistry
    Volume54
    Issue number3
    DOIs
    Publication statusPublished - 1998

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