Magnetic anisotropy of polycrystalline magnetoferritin investigated by SQUID and electron magnetic resonance

F. Moro, R. De Miguel, M. Jenkins, C. Gómez-Moreno, D. Sells, F. Tuna, E. J L McInnes, A. Lostao, F. Luis, J. Van Slageren

    Research output: Contribution to journalArticlepeer-review

    Abstract

    Magnetoferritin molecules with an average inorganic core diameter of 5.7±1.6 nm and polycrystalline internal structure were investigated by a combination of transmission electron microscopy, magnetic susceptibility, magnetization, and electron magnetic resonance (EMR) experiments. The temperature and frequency dependence of the magnetic susceptibility allowed for the determination of the magnetic anisotropy on an experimental time scale which spans from seconds to nanoseconds. In addition, angle-dependent EMR experiments were carried out for the determination of the nanoparticle symmetry and internal magnetic field. Due to the large surface to volume ratio, the nanoparticles show larger and uniaxial rather than cubic magnetic anisotropies compared to bulk maghemite and magnetite. © 2014 Elsevier B.V.
    Original languageEnglish
    Pages (from-to)188-196
    Number of pages8
    JournalJournal of Magnetism and Magnetic Materials
    Volume361
    DOIs
    Publication statusPublished - 2014

    Keywords

    • Electron magnetic resonance
    • Magnetic anisotropy
    • Magnetoferritin
    • SQUID

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