Matrix-assisted diffusion-ordered NMR spectroscopy with an invisible, tuneable matrix

Aaron Hernandez Cid; Ralph Adams; Mathias Nilsson; Katarzyna Piekarska; R Evans; Gareth Morris

doi:10.1039/C7RA00188F

Matrix-assisted diffusion-ordered NMR spectroscopy with an invisible, tuneable matrix

Aaron Hernandez Cid, Ralph Adams, Mathias Nilsson, Katarzyna Piekarska, R Evans, Gareth Morris

Research output: Contribution to journal › Article › peer-review

Abstract

Mixtures of species of similar sizes can be analysed with 1H NMR using diffusion-ordered spectroscopy (DOSY), by adding a co-solute with which different analytes interact to different extents (“matrix-assisted DOSY”). A matrix containing aqueous perfluorooctanoate micelles has the dual advantages of invisibility to 1H NMR, and interactions tuneable by adjusting the pH.

Original language	English
Pages (from-to)	10757-10762
Number of pages	6
Journal	RSC Advances
Volume	2017
Issue number	18
Early online date	8 Feb 2017
DOIs	https://doi.org/10.1039/C7RA00188F
Publication status	Published - 2017

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title = "Matrix-assisted diffusion-ordered NMR spectroscopy with an invisible, tuneable matrix",

abstract = "Mixtures of species of similar sizes can be analysed with 1H NMR using diffusion-ordered spectroscopy (DOSY), by adding a co-solute with which different analytes interact to different extents (“matrix-assisted DOSY”). A matrix containing aqueous perfluorooctanoate micelles has the dual advantages of invisibility to 1H NMR, and interactions tuneable by adjusting the pH.",

author = "{Hernandez Cid}, Aaron and Ralph Adams and Mathias Nilsson and Katarzyna Piekarska and R Evans and Gareth Morris",

year = "2017",

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AU - Adams, Ralph

AU - Nilsson, Mathias

AU - Piekarska, Katarzyna

AU - Evans, R

AU - Morris, Gareth

PY - 2017

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AB - Mixtures of species of similar sizes can be analysed with 1H NMR using diffusion-ordered spectroscopy (DOSY), by adding a co-solute with which different analytes interact to different extents (“matrix-assisted DOSY”). A matrix containing aqueous perfluorooctanoate micelles has the dual advantages of invisibility to 1H NMR, and interactions tuneable by adjusting the pH.

U2 - 10.1039/C7RA00188F

DO - 10.1039/C7RA00188F

M3 - Article

SN - 2046-2069

VL - 2017

SP - 10757

EP - 10762

JO - RSC Advances

JF - RSC Advances

IS - 18

ER -

Matrix-assisted diffusion-ordered NMR spectroscopy with an invisible, tuneable matrix

Abstract

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