Mechanistic insight into halide oxidation by non-heme iron complexes. Haloperoxidase versus halogenase activity

Anil Kumar Vardhaman; Prasenjit Barman; Suresh Kumar; Chivukula V. Sastri; Devesh Kumar; Sam P. De Visser

doi:10.1039/c3cc46792a

Mechanistic insight into halide oxidation by non-heme iron complexes. Haloperoxidase versus halogenase activity

Anil Kumar Vardhaman, Prasenjit Barman, Suresh Kumar, Chivukula V. Sastri, Devesh Kumar, Sam P. De Visser

Research output: Contribution to journal › Article › peer-review

Abstract

This work presents the first detailed study on mechanistic aspects of halide oxidation by non-heme iron complexes. We show that while iron(iii)-hydroperoxo complexes oxidise halides via oxygen atom transfer, the corresponding iron(iv)-oxo complex reacts via electron transfer. This journal is © The Royal Society of Chemistry 2013.

Original language	English
Pages (from-to)	10926-10928
Number of pages	2
Journal	Chemical Communications
Volume	49
Issue number	93
DOIs	https://doi.org/10.1039/c3cc46792a
Publication status	Published - 4 Dec 2013

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title = "Mechanistic insight into halide oxidation by non-heme iron complexes. Haloperoxidase versus halogenase activity",

abstract = "This work presents the first detailed study on mechanistic aspects of halide oxidation by non-heme iron complexes. We show that while iron(iii)-hydroperoxo complexes oxidise halides via oxygen atom transfer, the corresponding iron(iv)-oxo complex reacts via electron transfer. This journal is {\textcopyright} The Royal Society of Chemistry 2013.",

author = "Vardhaman, {Anil Kumar} and Prasenjit Barman and Suresh Kumar and Sastri, {Chivukula V.} and Devesh Kumar and {De Visser}, {Sam P.}",

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AU - Vardhaman, Anil Kumar

AU - Barman, Prasenjit

AU - Kumar, Suresh

AU - Sastri, Chivukula V.

AU - Kumar, Devesh

AU - De Visser, Sam P.

N1 - cited By 4

PY - 2013/12/4

Y1 - 2013/12/4

N2 - This work presents the first detailed study on mechanistic aspects of halide oxidation by non-heme iron complexes. We show that while iron(iii)-hydroperoxo complexes oxidise halides via oxygen atom transfer, the corresponding iron(iv)-oxo complex reacts via electron transfer. This journal is © The Royal Society of Chemistry 2013.

AB - This work presents the first detailed study on mechanistic aspects of halide oxidation by non-heme iron complexes. We show that while iron(iii)-hydroperoxo complexes oxidise halides via oxygen atom transfer, the corresponding iron(iv)-oxo complex reacts via electron transfer. This journal is © The Royal Society of Chemistry 2013.

U2 - 10.1039/c3cc46792a

DO - 10.1039/c3cc46792a

M3 - Article

SN - 1359-7345

VL - 49

SP - 10926

EP - 10928

JO - Chemical Communications

JF - Chemical Communications

IS - 93

ER -

Mechanistic insight into halide oxidation by non-heme iron complexes. Haloperoxidase versus halogenase activity

Abstract

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