Mechanistic observations on the unusual reactivity of dioxenone photosubstrates in the synthesis of ingenol

Jeffrey D. Winkler, Sean J. Harrison, Michael F. Greaney, Meagan B. Rouse

    Research output: Contribution to journalArticlepeer-review

    Abstract

    The irradiation of allylically substituted dioxenone photosubstrates 6 and 21 lead to unexpected products, the formation of which can be explained by a series of transannular hydrogen atom abstractions.
    Original languageEnglish
    Pages (from-to)2150-2154
    Number of pages4
    JournalSynthesis: journal of synthetic organic chemistry
    Issue number14
    DOIs
    Publication statusPublished - 2002

    Keywords

    • Cycloadditions
    • Natural products
    • Photochemistry
    • Radicais
    • Rearrangements

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