Meisenheimer complexes positively characterized as stable intermediates in the gas phase

Barbara Chiavarino; Maria Elisa Crestoni; Simonetta Fornarini; Francesco Lanucara; Joel Lemaire; Philippe Maître

doi:10.1002/anie.200604630

Meisenheimer complexes positively characterized as stable intermediates in the gas phase

Barbara Chiavarino, Maria Elisa Crestoni, Simonetta Fornarini, Francesco Lanucara, Joel Lemaire, Philippe Maître

Research output: Contribution to journal › Article › peer-review

Abstract

(Graph Presented) Proof positive: Infrared multiphoton dissociation (IRMPD) spectroscopy, with the tunable IR radiation of a free-electron laser source, provides positive identification of alkoxide adducts of 1,3,5-trinitrobenzene as prototypical anionic o complexes in the gas phase (see calculated IR spectrum of 1 under the experimental IRMPD spectrum; N blue, O green, Cgray, H light gray). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

Original language	English
Pages (from-to)	1995-1998
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	12
DOIs	https://doi.org/10.1002/anie.200604630
Publication status	Published - 2007

Keywords

Anionic σ
Complexes
IR spectroscopy
Mass spectrometry
Photodissociation
Structure elucidation

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10.1002/anie.200604630

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title = "Meisenheimer complexes positively characterized as stable intermediates in the gas phase",

abstract = "(Graph Presented) Proof positive: Infrared multiphoton dissociation (IRMPD) spectroscopy, with the tunable IR radiation of a free-electron laser source, provides positive identification of alkoxide adducts of 1,3,5-trinitrobenzene as prototypical anionic o complexes in the gas phase (see calculated IR spectrum of 1 under the experimental IRMPD spectrum; N blue, O green, Cgray, H light gray). {\textcopyright} 2007 Wiley-VCH Verlag GmbH & Co. KGaA.",

keywords = "Anionic σ, Complexes, IR spectroscopy, Mass spectrometry, Photodissociation, Structure elucidation",

author = "Barbara Chiavarino and Crestoni, {Maria Elisa} and Simonetta Fornarini and Francesco Lanucara and Joel Lemaire and Philippe Ma{\^i}tre",

year = "2007",

doi = "10.1002/anie.200604630",

language = "English",

volume = "46",

pages = "1995--1998",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley & Sons Ltd",

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TY - JOUR

T1 - Meisenheimer complexes positively characterized as stable intermediates in the gas phase

AU - Chiavarino, Barbara

AU - Crestoni, Maria Elisa

AU - Fornarini, Simonetta

AU - Lanucara, Francesco

AU - Lemaire, Joel

AU - Maître, Philippe

PY - 2007

Y1 - 2007

N2 - (Graph Presented) Proof positive: Infrared multiphoton dissociation (IRMPD) spectroscopy, with the tunable IR radiation of a free-electron laser source, provides positive identification of alkoxide adducts of 1,3,5-trinitrobenzene as prototypical anionic o complexes in the gas phase (see calculated IR spectrum of 1 under the experimental IRMPD spectrum; N blue, O green, Cgray, H light gray). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

AB - (Graph Presented) Proof positive: Infrared multiphoton dissociation (IRMPD) spectroscopy, with the tunable IR radiation of a free-electron laser source, provides positive identification of alkoxide adducts of 1,3,5-trinitrobenzene as prototypical anionic o complexes in the gas phase (see calculated IR spectrum of 1 under the experimental IRMPD spectrum; N blue, O green, Cgray, H light gray). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

KW - Anionic σ

KW - Complexes

KW - IR spectroscopy

KW - Mass spectrometry

KW - Photodissociation

KW - Structure elucidation

U2 - 10.1002/anie.200604630

DO - 10.1002/anie.200604630

M3 - Article

SN - 1433-7851

VL - 46

SP - 1995

EP - 1998

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 12

ER -

Meisenheimer complexes positively characterized as stable intermediates in the gas phase

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Keywords

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