[Mn6] under pressure: A combined crystallographic and magnetic study

Alessandro Prescimone; Constantinos J. Milios; Stephen Moggach; John E. Warren; Alistair R. Lennie; Javier Sanchez-Benitez; Konstantin Kamenev; Roland Bircher; Mark Murrie; Simon Parsons; Euan K. Brechin

doi:10.1002/anie.200705819

[Mn6] under pressure: A combined crystallographic and magnetic study

Alessandro Prescimone, Constantinos J. Milios, Stephen Moggach, John E. Warren, Alistair R. Lennie, Javier Sanchez-Benitez, Konstantin Kamenev, Roland Bircher, Mark Murrie, Simon Parsons, Euan K. Brechin

Research output: Contribution to journal › Article › peer-review

Abstract

Folding under pressure: High-pressure crystallography of an Mn6 single-molecule magnet reveals dramatic changes in the intramolecular geometry of the magnetic core (see picture; Mn purple, O red, N blue). These structural changes effect the magnetic properties of the molecule: the magnitude of the ferromagnetic exchange between the metals is decreased, and under extreme pressure switches to antiferromagnetic. (Figure Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

Original language	English
Pages (from-to)	2828-2831
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	15
DOIs	https://doi.org/10.1002/anie.200705819
Publication status	Published - 31 Mar 2008

Keywords

High-pressure chemistry
Magnetic properties
Manganese
Single-molecule magnets
Solid-state structures

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10.1002/anie.200705819

http://www3.interscience.wiley.com/cgi-bin/fulltext/117928507/PDFSTART

CCDC 671314: Experimental Crystal Structure Determination
Prescimone, A. (Contributor), Milios, C. J. (Contributor), Moggach, S. A. (Contributor), Warren, J. (Contributor), Lennie, A. R. (Contributor), Sanchez-Benitez, J. (Contributor), Kamenev, K. V. (Contributor), Bircher, R. (Contributor), Murrie, M. (Contributor), Parsons, S. (Contributor) & Brechin, E. K. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2008
DOI: 10.5517/ccqjk92, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccqjk92&sid=DataCite
Dataset
CCDC 671313: Experimental Crystal Structure Determination
Prescimone, A. (Contributor), Milios, C. J. (Contributor), Moggach, S. A. (Contributor), Warren, J. (Contributor), Lennie, A. R. (Contributor), Sanchez-Benitez, J. (Contributor), Kamenev, K. V. (Contributor), Bircher, R. (Contributor), Murrie, M. (Contributor), Parsons, S. (Contributor) & Brechin, E. K. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2008
DOI: 10.5517/ccqjk81, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccqjk81&sid=DataCite
Dataset
CCDC 671315: Experimental Crystal Structure Determination
Prescimone, A. (Contributor), Milios, C. J. (Contributor), Moggach, S. A. (Contributor), Warren, J. (Contributor), Lennie, A. R. (Contributor), Sanchez-Benitez, J. (Contributor), Kamenev, K. V. (Contributor), Bircher, R. (Contributor), Murrie, M. (Contributor), Parsons, S. (Contributor) & Brechin, E. K. (Contributor), Cambridge Crystallographic Data Centre, 2007
DOI: 10.5517/ccqjkb3, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccqjkb3&sid=DataCite
Dataset

Cite this

@article{815e3f9d6c8c43dca3198341f38b3bec,

title = "[Mn6] under pressure: A combined crystallographic and magnetic study",

abstract = "Folding under pressure: High-pressure crystallography of an Mn6 single-molecule magnet reveals dramatic changes in the intramolecular geometry of the magnetic core (see picture; Mn purple, O red, N blue). These structural changes effect the magnetic properties of the molecule: the magnitude of the ferromagnetic exchange between the metals is decreased, and under extreme pressure switches to antiferromagnetic. (Figure Presented). {\textcopyright} 2008 Wiley-VCH Verlag GmbH & Co. KGaA.",

keywords = "High-pressure chemistry, Magnetic properties, Manganese, Single-molecule magnets, Solid-state structures",

author = "Alessandro Prescimone and Milios, {Constantinos J.} and Stephen Moggach and Warren, {John E.} and Lennie, {Alistair R.} and Javier Sanchez-Benitez and Konstantin Kamenev and Roland Bircher and Mark Murrie and Simon Parsons and Brechin, {Euan K.}",

note = "15",

year = "2008",

month = mar,

day = "31",

doi = "10.1002/anie.200705819",

language = "English",

volume = "47",

pages = "2828--2831",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley & Sons Ltd",

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TY - JOUR

T1 - [Mn6] under pressure: A combined crystallographic and magnetic study

AU - Prescimone, Alessandro

AU - Milios, Constantinos J.

AU - Moggach, Stephen

AU - Warren, John E.

AU - Lennie, Alistair R.

AU - Sanchez-Benitez, Javier

AU - Kamenev, Konstantin

AU - Bircher, Roland

AU - Murrie, Mark

AU - Parsons, Simon

AU - Brechin, Euan K.

N1 - 15

PY - 2008/3/31

Y1 - 2008/3/31

N2 - Folding under pressure: High-pressure crystallography of an Mn6 single-molecule magnet reveals dramatic changes in the intramolecular geometry of the magnetic core (see picture; Mn purple, O red, N blue). These structural changes effect the magnetic properties of the molecule: the magnitude of the ferromagnetic exchange between the metals is decreased, and under extreme pressure switches to antiferromagnetic. (Figure Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

AB - Folding under pressure: High-pressure crystallography of an Mn6 single-molecule magnet reveals dramatic changes in the intramolecular geometry of the magnetic core (see picture; Mn purple, O red, N blue). These structural changes effect the magnetic properties of the molecule: the magnitude of the ferromagnetic exchange between the metals is decreased, and under extreme pressure switches to antiferromagnetic. (Figure Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

KW - High-pressure chemistry

KW - Magnetic properties

KW - Manganese

KW - Single-molecule magnets

KW - Solid-state structures

U2 - 10.1002/anie.200705819

DO - 10.1002/anie.200705819

M3 - Article

SN - 1433-7851

VL - 47

SP - 2828

EP - 2831

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 15

ER -

[Mn6] under pressure: A combined crystallographic and magnetic study

Abstract

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Datasets

CCDC 671314: Experimental Crystal Structure Determination

CCDC 671313: Experimental Crystal Structure Determination

CCDC 671315: Experimental Crystal Structure Determination

Cite this