Multi-color resonance ionization of laser ablated gadolinium at high laser power

J. Maul, K. Eberhardt, G. Huber, S. Karpuk, G. Passler, M.C. Roca-Saiz, Ilya Strashnov, N. Trautmann, K. Wendt

    Research output: Contribution to journalArticlepeer-review

    Abstract

    Spectroscopic and analytical properties of a trace analytical method using multi-step resonance ionization at high laser intensities (>kW/cm2) have been investigated with gadolinium as a test element. Strongly saturated transitions are observed, which have been used for a temperature determination of the atoms in the laser ablated plume. Regimes of multi-step resonance ionization and multiphoton ionization could be distinguished. Analytical performances due to resonance enhancement and resulting discrimination against non-resonant background, precision in isotope ratio determination and overall detection efficiency are discussed.
    Original languageEnglish
    Pages (from-to)364-372
    Number of pages9
    JournalOptics Communications
    Volume256
    Issue number4-6
    DOIs
    Publication statusPublished - 14 Mar 2005

    Keywords

    • laser ablation
    • resonance ionization spectroscopy
    • MALDI-TOF

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