Abstract
Spectroscopic and analytical properties of a trace analytical method using multi-step resonance ionization at high laser intensities (>kW/cm2) have been investigated with gadolinium as a test element. Strongly saturated transitions are observed, which have been used for a temperature determination of the atoms in the laser ablated plume. Regimes of multi-step resonance ionization and multiphoton ionization could be distinguished. Analytical performances due to resonance enhancement and resulting discrimination against non-resonant background, precision in isotope ratio determination and overall detection efficiency are discussed.
Original language | English |
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Pages (from-to) | 364-372 |
Number of pages | 9 |
Journal | Optics Communications |
Volume | 256 |
Issue number | 4-6 |
DOIs | |
Publication status | Published - 14 Mar 2005 |
Keywords
- laser ablation
- resonance ionization spectroscopy
- MALDI-TOF