[N-(2-Aminoethyl)-N-(2-{(E)-[9-(diethoxymethyl)- 1,10-phenanthrolin-2-yl]- methylideneamino}ethyl)ethane-1,2-diamine]copper(II) bis(perchlorate)

Hassan Keypour, Hamid Goudarziafshar, Alan K. Brisdon, Robin G. Pritchard

    Research output: Contribution to journalArticlepeer-review

    Abstract

    In the title compound, [Cu(C24H34N6O2)](ClO4)2, the copper(II) coordination geometry is intermediate between square-based-pyramidal and trigonal-bipyramidal. The H atoms of the sixth non-metal-coordinating nitro-gen donor engage in intra-molecular hydrogen bonding with the eth-oxy O atom and the uncoordinated phenanthroline N atom. Hydrogen bonding is also observed between the NH2 H atoms and two of the phenanthroline H atoms with the perchlorate anions. © International Union of Crystallography 2007.
    Original languageEnglish
    Pages (from-to)m2158-m2159
    JournalActa Crystallographica Section E: Structure Reports Online
    Volume63
    Issue number8
    DOIs
    Publication statusPublished - 31 Jul 2007

    Keywords

    • Hydrogen bond (in copper (aminoethyl)({[(diethoxymethyl)phenanthrolinyl]methylideneamino}ethyl)ethanediamine complex perchlorate salt)
    • Crystal structure
    • Molecular structure (of copper (aminoethyl)({[(diethoxymethyl)phenanthrolinyl]methylideneamino}ethyl)ethanediamine complex perchlorate salt)
    • mol structure copper aminoethyldiethoxymethylphenanthrolinylmethylideneaminoethylethanediamine perchlorate
    • crystal structure copper aminoethyldiethoxymethylphenanthrolinylmethylideneaminoethylethanediamine perchlorate
    • hydrogen bond copper aminoethyldiethoxymethylphenanthrolinylmethylideneaminoethylethanediamine perchlorate

    Fingerprint

    Dive into the research topics of '[N-(2-Aminoethyl)-N-(2-{(E)-[9-(diethoxymethyl)- 1,10-phenanthrolin-2-yl]- methylideneamino}ethyl)ethane-1,2-diamine]copper(II) bis(perchlorate)'. Together they form a unique fingerprint.

    Cite this