(N-heterocyclic carbene)-Pd catalyzed synthesis of poly(triarylamine)s by Buchwald-Hartwig coupling of aryl chlorides

Mario Hoyos; Reiner Sebastian Sprick; Chao Wang; Michael Lewis Turner; Oscar Navarro

doi:10.1002/pola.26239

(N-heterocyclic carbene)-Pd catalyzed synthesis of poly(triarylamine)s by Buchwald-Hartwig coupling of aryl chlorides

Mario Hoyos, Reiner Sebastian Sprick, Chao Wang, Michael Lewis Turner, Oscar Navarro

Research output: Contribution to journal › Article › peer-review

Abstract

The use of an air and moisture stable, commercially available (N-heterocyclic carbene)-Pd complex as precatalyst allows for the unprecedented Buchwald-Hartwig polyamination of aryl chlorides with primary amines. Different approaches for the end-capping of the polymers have also been evaluated. Copyright © 2012 Wiley Periodicals, Inc. © 2012 Wiley Periodicals, Inc.

Original language	English
Pages (from-to)	4155-4160
Number of pages	5
Journal	Journal of Polymer Science. Part A: Polymer Chemistry
Volume	50
Issue number	20
DOIs	https://doi.org/10.1002/pola.26239
Publication status	Published - 15 Oct 2012

Keywords

Buchwald-Hartwig coupling
catalysis
N-heterocyclic carbene
polyamine
semiconducting polymer

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10.1002/pola.26239

http://doi.wiley.com/10.1002/pola.26239

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title = "(N-heterocyclic carbene)-Pd catalyzed synthesis of poly(triarylamine)s by Buchwald-Hartwig coupling of aryl chlorides",

abstract = "The use of an air and moisture stable, commercially available (N-heterocyclic carbene)-Pd complex as precatalyst allows for the unprecedented Buchwald-Hartwig polyamination of aryl chlorides with primary amines. Different approaches for the end-capping of the polymers have also been evaluated. Copyright {\textcopyright} 2012 Wiley Periodicals, Inc. {\textcopyright} 2012 Wiley Periodicals, Inc.",

keywords = "Buchwald-Hartwig coupling, catalysis, N-heterocyclic carbene, polyamine, semiconducting polymer",

author = "Mario Hoyos and Sprick, {Reiner Sebastian} and Chao Wang and Turner, {Michael Lewis} and Oscar Navarro",

year = "2012",

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language = "English",

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journal = "Journal of Polymer Science. Part A: Polymer Chemistry",

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AU - Hoyos, Mario

AU - Sprick, Reiner Sebastian

AU - Wang, Chao

AU - Turner, Michael Lewis

AU - Navarro, Oscar

PY - 2012/10/15

Y1 - 2012/10/15

N2 - The use of an air and moisture stable, commercially available (N-heterocyclic carbene)-Pd complex as precatalyst allows for the unprecedented Buchwald-Hartwig polyamination of aryl chlorides with primary amines. Different approaches for the end-capping of the polymers have also been evaluated. Copyright © 2012 Wiley Periodicals, Inc. © 2012 Wiley Periodicals, Inc.

AB - The use of an air and moisture stable, commercially available (N-heterocyclic carbene)-Pd complex as precatalyst allows for the unprecedented Buchwald-Hartwig polyamination of aryl chlorides with primary amines. Different approaches for the end-capping of the polymers have also been evaluated. Copyright © 2012 Wiley Periodicals, Inc. © 2012 Wiley Periodicals, Inc.

KW - Buchwald-Hartwig coupling

KW - catalysis

KW - N-heterocyclic carbene

KW - polyamine

KW - semiconducting polymer

U2 - 10.1002/pola.26239

DO - 10.1002/pola.26239

M3 - Article

SN - 1099-0518

VL - 50

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JO - Journal of Polymer Science. Part A: Polymer Chemistry

JF - Journal of Polymer Science. Part A: Polymer Chemistry

IS - 20

ER -

(N-heterocyclic carbene)-Pd catalyzed synthesis of poly(triarylamine)s by Buchwald-Hartwig coupling of aryl chlorides

Abstract

Keywords

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