(N-heterocyclic carbene)PdCl2(TEA) complexes: Studies on the effect of the "throw-away" ligand in catalytic activity

Ming Tsz Chen; David A. Vicic; Michael L. Turner; Oscar Navarro

doi:10.1021/om200699p

(N-heterocyclic carbene)PdCl2(TEA) complexes: Studies on the effect of the "throw-away" ligand in catalytic activity

Ming Tsz Chen, David A. Vicic, Michael L. Turner, Oscar Navarro

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis and characterization of a series of (N-heterocyclic carbene)PdCl2(TEA) (TEA = triethylamine) complexes are presented. A comparison of their activity in the Suzuki-Miyaura and Buchwald-Hartwig reactions with similar (N-heterocyclic carbene)Pd(II) complexes is also presented. © 2011 American Chemical Society.

Original language	English
Pages (from-to)	5052-5056
Number of pages	4
Journal	Organometallics
Volume	30
Issue number	18
DOIs	https://doi.org/10.1021/om200699p
Publication status	Published - 26 Sept 2011

Keywords

catalyst
conjugated oligomer
synthesis

Access to Document

10.1021/om200699p

http://pubs.acs.org/doi/abs/10.1021/om200699p

CCDC 855512: Experimental Crystal Structure Determination
Chen, M. T. (Contributor), Vicic, D. A. (Contributor), Turner, M. (Contributor) & Navarro, O. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2012
DOI: 10.5517/ccxq750, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccxq750&sid=DataCite
Dataset
CCDC 855514: Experimental Crystal Structure Determination
Chen, M. T. (Contributor), Vicic, D. A. (Contributor), Turner, M. (Contributor) & Navarro, O. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2012
DOI: 10.5517/ccxq772, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccxq772&sid=DataCite
Dataset
CCDC 855513: Experimental Crystal Structure Determination
Chen, M. T. (Contributor), Vicic, D. A. (Contributor), Turner, M. (Contributor) & Navarro, O. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2012
DOI: 10.5517/ccxq761, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccxq761&sid=DataCite
Dataset

Cite this

@article{6cdeb29bf9384de2b23f1b8b308b53c4,

title = "(N-heterocyclic carbene)PdCl2(TEA) complexes: Studies on the effect of the {"}throw-away{"} ligand in catalytic activity",

abstract = "The synthesis and characterization of a series of (N-heterocyclic carbene)PdCl2(TEA) (TEA = triethylamine) complexes are presented. A comparison of their activity in the Suzuki-Miyaura and Buchwald-Hartwig reactions with similar (N-heterocyclic carbene)Pd(II) complexes is also presented. {\textcopyright} 2011 American Chemical Society.",

keywords = "catalyst, conjugated oligomer, synthesis",

author = "Chen, {Ming Tsz} and Vicic, {David A.} and Turner, {Michael L.} and Oscar Navarro",

year = "2011",

month = sep,

day = "26",

doi = "10.1021/om200699p",

language = "English",

volume = "30",

pages = "5052--5056",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "18",

}

TY - JOUR

T1 - (N-heterocyclic carbene)PdCl2(TEA) complexes: Studies on the effect of the "throw-away" ligand in catalytic activity

AU - Chen, Ming Tsz

AU - Vicic, David A.

AU - Turner, Michael L.

AU - Navarro, Oscar

PY - 2011/9/26

Y1 - 2011/9/26

N2 - The synthesis and characterization of a series of (N-heterocyclic carbene)PdCl2(TEA) (TEA = triethylamine) complexes are presented. A comparison of their activity in the Suzuki-Miyaura and Buchwald-Hartwig reactions with similar (N-heterocyclic carbene)Pd(II) complexes is also presented. © 2011 American Chemical Society.

AB - The synthesis and characterization of a series of (N-heterocyclic carbene)PdCl2(TEA) (TEA = triethylamine) complexes are presented. A comparison of their activity in the Suzuki-Miyaura and Buchwald-Hartwig reactions with similar (N-heterocyclic carbene)Pd(II) complexes is also presented. © 2011 American Chemical Society.

KW - catalyst

KW - conjugated oligomer

KW - synthesis

U2 - 10.1021/om200699p

DO - 10.1021/om200699p

M3 - Article

SN - 0276-7333

VL - 30

SP - 5052

EP - 5056

JO - Organometallics

JF - Organometallics

IS - 18

ER -

(N-heterocyclic carbene)PdCl2(TEA) complexes: Studies on the effect of the "throw-away" ligand in catalytic activity

Abstract

Keywords

Access to Document

Fingerprint

Datasets

CCDC 855512: Experimental Crystal Structure Determination

CCDC 855514: Experimental Crystal Structure Determination

CCDC 855513: Experimental Crystal Structure Determination

Cite this