Nanoparticles and thin films of silver from complexes of derivatives of N-(diisopropylthiophosphoryl) thioureas

Damir A. Safin; Phumlane S. Mdluli; Neerish Revaprasadu; Kibriya Ahmad; Mohammad Afzaal; Madeleine Helliwell; Paul O'Brien; Elmira R. Shakirova; Maria G. Babashkina; Axel Klein

doi:10.1021/cm901200h

Nanoparticles and thin films of silver from complexes of derivatives of N-(diisopropylthiophosphoryl) thioureas

Damir A. Safin, Phumlane S. Mdluli, Neerish Revaprasadu, Kibriya Ahmad, Mohammad Afzaal, Madeleine Helliwell, Paul O'Brien, Elmira R. Shakirova, Maria G. Babashkina, Axel Klein

Research output: Contribution to journal › Article › peer-review

Abstract

The derivatives of JV-(diisopropylthiophosphoryl)thiourea RC(S)NHP(S)(OiPr)2 (R = C5H11N, C5H6N2 or C10H7NH 2) followed by their complexation with silver are reported. All complexes are decomposed in hot hexadecylamine (HDA) to give HDA-capped silver nanoparticles. The absorption spectra of the HDA-capped silver nanoparticles exhibit surface plasmon resonance (SPR) absorption in the 400-420 nm region. Transmission electron microscopy (TEM) images of all particles are close to spherical in shape; with sizes ranging from 17 to 20 nm. The X-ray diffraction (XRD) patterns of the silver nanoparticles obtained from all three complexes could be indexed to face centered cubic silver. Scanning electron microscopy (SEM) image confirmed the spherical shape of the particles. The silver complex of 1-naphthylamine was also used to deposit thin films of silver by the aerosol-assisted chemical vapor deposition (AACVD). © 2009 American Chemical Society.

Original language	English
Pages (from-to)	4233-4240
Number of pages	7
Journal	Chemistry of Materials
Volume	21
Issue number	18
DOIs	https://doi.org/10.1021/cm901200h
Publication status	Published - 22 Sept 2009

Access to Document

10.1021/cm901200h

http://pubs.acs.org/doi/pdfplus/10.1021/cm901200h

Cite this

@article{983eb84e241547658c772752a4a199fe,

title = "Nanoparticles and thin films of silver from complexes of derivatives of N-(diisopropylthiophosphoryl) thioureas",

abstract = "The derivatives of JV-(diisopropylthiophosphoryl)thiourea RC(S)NHP(S)(OiPr)2 (R = C5H11N, C5H6N2 or C10H7NH 2) followed by their complexation with silver are reported. All complexes are decomposed in hot hexadecylamine (HDA) to give HDA-capped silver nanoparticles. The absorption spectra of the HDA-capped silver nanoparticles exhibit surface plasmon resonance (SPR) absorption in the 400-420 nm region. Transmission electron microscopy (TEM) images of all particles are close to spherical in shape; with sizes ranging from 17 to 20 nm. The X-ray diffraction (XRD) patterns of the silver nanoparticles obtained from all three complexes could be indexed to face centered cubic silver. Scanning electron microscopy (SEM) image confirmed the spherical shape of the particles. The silver complex of 1-naphthylamine was also used to deposit thin films of silver by the aerosol-assisted chemical vapor deposition (AACVD). {\textcopyright} 2009 American Chemical Society.",

author = "Safin, \{Damir A.\} and Mdluli, \{Phumlane S.\} and Neerish Revaprasadu and Kibriya Ahmad and Mohammad Afzaal and Madeleine Helliwell and Paul O'Brien and Shakirova, \{Elmira R.\} and Babashkina, \{Maria G.\} and Axel Klein",

year = "2009",

month = sep,

day = "22",

doi = "10.1021/cm901200h",

language = "English",

volume = "21",

pages = "4233--4240",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "American Chemical Society",

number = "18",

}

TY - JOUR

T1 - Nanoparticles and thin films of silver from complexes of derivatives of N-(diisopropylthiophosphoryl) thioureas

AU - Safin, Damir A.

AU - Mdluli, Phumlane S.

AU - Revaprasadu, Neerish

AU - Ahmad, Kibriya

AU - Afzaal, Mohammad

AU - Helliwell, Madeleine

AU - O'Brien, Paul

AU - Shakirova, Elmira R.

AU - Babashkina, Maria G.

AU - Klein, Axel

PY - 2009/9/22

Y1 - 2009/9/22

N2 - The derivatives of JV-(diisopropylthiophosphoryl)thiourea RC(S)NHP(S)(OiPr)2 (R = C5H11N, C5H6N2 or C10H7NH 2) followed by their complexation with silver are reported. All complexes are decomposed in hot hexadecylamine (HDA) to give HDA-capped silver nanoparticles. The absorption spectra of the HDA-capped silver nanoparticles exhibit surface plasmon resonance (SPR) absorption in the 400-420 nm region. Transmission electron microscopy (TEM) images of all particles are close to spherical in shape; with sizes ranging from 17 to 20 nm. The X-ray diffraction (XRD) patterns of the silver nanoparticles obtained from all three complexes could be indexed to face centered cubic silver. Scanning electron microscopy (SEM) image confirmed the spherical shape of the particles. The silver complex of 1-naphthylamine was also used to deposit thin films of silver by the aerosol-assisted chemical vapor deposition (AACVD). © 2009 American Chemical Society.

AB - The derivatives of JV-(diisopropylthiophosphoryl)thiourea RC(S)NHP(S)(OiPr)2 (R = C5H11N, C5H6N2 or C10H7NH 2) followed by their complexation with silver are reported. All complexes are decomposed in hot hexadecylamine (HDA) to give HDA-capped silver nanoparticles. The absorption spectra of the HDA-capped silver nanoparticles exhibit surface plasmon resonance (SPR) absorption in the 400-420 nm region. Transmission electron microscopy (TEM) images of all particles are close to spherical in shape; with sizes ranging from 17 to 20 nm. The X-ray diffraction (XRD) patterns of the silver nanoparticles obtained from all three complexes could be indexed to face centered cubic silver. Scanning electron microscopy (SEM) image confirmed the spherical shape of the particles. The silver complex of 1-naphthylamine was also used to deposit thin films of silver by the aerosol-assisted chemical vapor deposition (AACVD). © 2009 American Chemical Society.

UR - https://www.scopus.com/pages/publications/70349456544

U2 - 10.1021/cm901200h

DO - 10.1021/cm901200h

M3 - Article

SN - 0897-4756

VL - 21

SP - 4233

EP - 4240

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 18

ER -

Nanoparticles and thin films of silver from complexes of derivatives of N-(diisopropylthiophosphoryl) thioureas

Abstract

Access to Document

Other files and links

Fingerprint

CCDC 1015649: Experimental Crystal Structure Determination

Cite this

Nanoparticles and thin films of silver from complexes of derivatives of N-(diisopropylthiophosphoryl) thioureas

Abstract

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 1015649: Experimental Crystal Structure Determination

Cite this