New series of indium formates: Hydrothermal synthesis, structure and coordination modes

J Su; Y X Wang; S Yang; G B Li; F H Liao; J H Lin

doi:10.1021/ic7007599

New series of indium formates: Hydrothermal synthesis, structure and coordination modes

J Su, Y X Wang, S Yang, G B Li, F H Liao, J H Lin

The University of Manchester

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Abstract

Three new indium(III) compounds, ln(HCOO)(3) (1), ln(2)(HCOO)(5)(OH) (2), and ln(HCOO)(2)(OH) (3), were synthesized under hydrothermal conditions and characterized by single crystal and powder X-ray diffraction experiments, as well as by IR spectroscopy, elemental analysis, and coupled TG-DSC-MS measurement. All of these compounds adopt 3D framework structures consisting of InO6 octahedra and the 2.11 binding modes of formate with the (syn, syn-; syn, anti-; anti, anti-) configurations. The structural investigation of these indium formates reveals that the gradual introduction of the hydroxyl groups into the structures induces the polymerization of the InO6 octahedra, that is, InO6 is isolated in 1, becomes dimeric in 2, and finally forms 1 D chains in 3. In addition, a simple formula that may be used for estimating the overall coordination number of the formate in M-a(HCOO)(b)L-c is proposed.

Original language	English
Pages (from-to)	8403-8409
Number of pages	7
Journal	Inorganic Chemistry: including bioinorganic chemistry
Volume	46
DOIs	https://doi.org/10.1021/ic7007599
Publication status	Published - 2007

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10.1021/ic7007599

CCDC 668883: Experimental Crystal Structure Determination
Su, J. (Contributor), Wang, Y. X. (Contributor), Yang, S. (Contributor), Li, G. B. (Contributor), Liao, F. H. (Contributor) & Lin, J. H. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2008
DOI: 10.5517/ccqg0w1, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccqg0w1&sid=DataCite
Dataset
CCDC 668882: Experimental Crystal Structure Determination
Su, J. (Contributor), Wang, Y. X. (Contributor), Yang, S. (Contributor), Li, G. B. (Contributor), Liao, F. H. (Contributor) & Lin, J. H. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2008
DOI: 10.5517/ccqg0v0, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccqg0v0&sid=DataCite
Dataset
CCDC 668881: Experimental Crystal Structure Determination
Su, J. (Contributor), Wang, Y. X. (Contributor), Yang, S. (Contributor), Li, G. B. (Contributor), Liao, F. H. (Contributor) & Lin, J. H. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2008
DOI: 10.5517/ccqg0tz, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccqg0tz&sid=DataCite
Dataset

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@article{ba35e2746e444cfa8d17018a263259b6,

title = "New series of indium formates: Hydrothermal synthesis, structure and coordination modes",

abstract = "Three new indium(III) compounds, ln(HCOO)(3) (1), ln(2)(HCOO)(5)(OH) (2), and ln(HCOO)(2)(OH) (3), were synthesized under hydrothermal conditions and characterized by single crystal and powder X-ray diffraction experiments, as well as by IR spectroscopy, elemental analysis, and coupled TG-DSC-MS measurement. All of these compounds adopt 3D framework structures consisting of InO6 octahedra and the 2.11 binding modes of formate with the (syn, syn-; syn, anti-; anti, anti-) configurations. The structural investigation of these indium formates reveals that the gradual introduction of the hydroxyl groups into the structures induces the polymerization of the InO6 octahedra, that is, InO6 is isolated in 1, becomes dimeric in 2, and finally forms 1 D chains in 3. In addition, a simple formula that may be used for estimating the overall coordination number of the formate in M-a(HCOO)(b)L-c is proposed.",

author = "J Su and Wang, {Y X} and S Yang and Li, {G B} and Liao, {F H} and Lin, {J H}",

note = "Times Cited: 10",

year = "2007",

doi = "10.1021/ic7007599",

language = "English",

volume = "46",

pages = "8403--8409",

journal = "Inorganic Chemistry: including bioinorganic chemistry ",

issn = "0020-1669",

publisher = "American Chemical Society",

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TY - JOUR

T1 - New series of indium formates: Hydrothermal synthesis, structure and coordination modes

AU - Su, J

AU - Wang, Y X

AU - Yang, S

AU - Li, G B

AU - Liao, F H

AU - Lin, J H

N1 - Times Cited: 10

PY - 2007

Y1 - 2007

N2 - Three new indium(III) compounds, ln(HCOO)(3) (1), ln(2)(HCOO)(5)(OH) (2), and ln(HCOO)(2)(OH) (3), were synthesized under hydrothermal conditions and characterized by single crystal and powder X-ray diffraction experiments, as well as by IR spectroscopy, elemental analysis, and coupled TG-DSC-MS measurement. All of these compounds adopt 3D framework structures consisting of InO6 octahedra and the 2.11 binding modes of formate with the (syn, syn-; syn, anti-; anti, anti-) configurations. The structural investigation of these indium formates reveals that the gradual introduction of the hydroxyl groups into the structures induces the polymerization of the InO6 octahedra, that is, InO6 is isolated in 1, becomes dimeric in 2, and finally forms 1 D chains in 3. In addition, a simple formula that may be used for estimating the overall coordination number of the formate in M-a(HCOO)(b)L-c is proposed.

AB - Three new indium(III) compounds, ln(HCOO)(3) (1), ln(2)(HCOO)(5)(OH) (2), and ln(HCOO)(2)(OH) (3), were synthesized under hydrothermal conditions and characterized by single crystal and powder X-ray diffraction experiments, as well as by IR spectroscopy, elemental analysis, and coupled TG-DSC-MS measurement. All of these compounds adopt 3D framework structures consisting of InO6 octahedra and the 2.11 binding modes of formate with the (syn, syn-; syn, anti-; anti, anti-) configurations. The structural investigation of these indium formates reveals that the gradual introduction of the hydroxyl groups into the structures induces the polymerization of the InO6 octahedra, that is, InO6 is isolated in 1, becomes dimeric in 2, and finally forms 1 D chains in 3. In addition, a simple formula that may be used for estimating the overall coordination number of the formate in M-a(HCOO)(b)L-c is proposed.

U2 - 10.1021/ic7007599

DO - 10.1021/ic7007599

M3 - Article

SN - 0020-1669

VL - 46

SP - 8403

EP - 8409

JO - Inorganic Chemistry: including bioinorganic chemistry

JF - Inorganic Chemistry: including bioinorganic chemistry

ER -

New series of indium formates: Hydrothermal synthesis, structure and coordination modes

Abstract

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CCDC 668883: Experimental Crystal Structure Determination

CCDC 668882: Experimental Crystal Structure Determination

CCDC 668881: Experimental Crystal Structure Determination

Cite this