Ni(III) vs. Ni(II)-thiyl radical: Charge-delocalisation in a binuclear Ni(III)Ni(II)-dithiolate complex

Neil D J Branscombe, Andrew J. Atkins, Armando Marin-Becerra, Eric J L McInnes, Frank E. Mabbs, Jonathan McMaster, Martin Schröder

    Research output: Contribution to journalArticlepeer-review

    Abstract

    Multi-frequency EPR spectroscopy on 61Ni-labelled samples of [Ni2(L)]3+ confirms extensive charge-delocalisation between the Ni(III) centre and thiolate donors in the Ni(II)Ni(III) complex.
    Original languageEnglish
    Pages (from-to)1098-1099
    Number of pages2
    JournalChemical Communications
    Volume9
    Issue number9
    DOIs
    Publication statusPublished - 7 May 2003

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