Nitrogen and hydrogen adsorption by an organic microporous crystal

Kadhum J. Msayib; David Book; Peter M. Budd; Nhamo Chaukura; Kenneth D M Harris; Madeleine Helliwell; Steven Tedds; Allan Walton; John E. Warren; Mingcan Xu; Neil B. McKeown

doi:10.1002/anie.200900234

Nitrogen and hydrogen adsorption by an organic microporous crystal

Kadhum J. Msayib, David Book, Peter M. Budd, Nhamo Chaukura, Kenneth D M Harris, Madeleine Helliwell, Steven Tedds, Allan Walton, John E. Warren, Mingcan Xu, Neil B. McKeown

Research output: Contribution to journal › Article › peer-review

Abstract

Quick on the uptake: Following its identification during a targeted search, the intriguing crystal structure of 3,3 ,4,4 -tetra(trimethylsilylethynyl) biphenyl was investigated. Simple removal of the included solvent provides an organic crystal with an open microporous structure that has a striking similarity to that of zeolite A (see picture). Reversible adsorption of nitrogen and hydrogen gases at 77 K confirms that the microporosity is permanent. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

Original language	English
Pages (from-to)	3273-3277
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	18
DOIs	https://doi.org/10.1002/anie.200900234
Publication status	Published - 20 Apr 2009

Keywords

Adsorption
Microporous materials (adsorption of nitrogen and hydrogen on org. microporous crystal)
adsorption nitrogen hydrogen org microporous crystal

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10.1002/anie.200900234

http://www3.interscience.wiley.com/cgi-bin/fulltext/122296620/PDFSTART

CCDC 713074: Experimental Crystal Structure Determination
Msayib, K. J. (Contributor), Book, D. (Contributor), Budd, P. (Contributor), Chaukura, N. (Contributor), Harris, K. D. M. (Contributor), Helliwell, M. (Contributor), Tedds, S. (Contributor), Walton, A. (Contributor), Warren, J. (Contributor), Xu, M. (Contributor) & Mckeown, N. B. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2010
DOI: 10.5517/ccry0d2, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccry0d2&sid=DataCite
Dataset

Cite this

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title = "Nitrogen and hydrogen adsorption by an organic microporous crystal",

abstract = "Quick on the uptake: Following its identification during a targeted search, the intriguing crystal structure of 3,3 ,4,4 -tetra(trimethylsilylethynyl) biphenyl was investigated. Simple removal of the included solvent provides an organic crystal with an open microporous structure that has a striking similarity to that of zeolite A (see picture). Reversible adsorption of nitrogen and hydrogen gases at 77 K confirms that the microporosity is permanent. {\textcopyright} 2009 Wiley-VCH Verlag GmbH & Co. KGaA.",

keywords = "Adsorption, Microporous materials (adsorption of nitrogen and hydrogen on org. microporous crystal), adsorption nitrogen hydrogen org microporous crystal",

author = "Msayib, {Kadhum J.} and David Book and Budd, {Peter M.} and Nhamo Chaukura and Harris, {Kenneth D M} and Madeleine Helliwell and Steven Tedds and Allan Walton and Warren, {John E.} and Mingcan Xu and McKeown, {Neil B.}",

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year = "2009",

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doi = "10.1002/anie.200900234",

language = "English",

volume = "48",

pages = "3273--3277",

journal = "Angewandte Chemie - International Edition",

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TY - JOUR

T1 - Nitrogen and hydrogen adsorption by an organic microporous crystal

AU - Msayib, Kadhum J.

AU - Book, David

AU - Budd, Peter M.

AU - Chaukura, Nhamo

AU - Harris, Kenneth D M

AU - Helliwell, Madeleine

AU - Tedds, Steven

AU - Walton, Allan

AU - Warren, John E.

AU - Xu, Mingcan

AU - McKeown, Neil B.

N1 - 18

PY - 2009/4/20

Y1 - 2009/4/20

N2 - Quick on the uptake: Following its identification during a targeted search, the intriguing crystal structure of 3,3 ,4,4 -tetra(trimethylsilylethynyl) biphenyl was investigated. Simple removal of the included solvent provides an organic crystal with an open microporous structure that has a striking similarity to that of zeolite A (see picture). Reversible adsorption of nitrogen and hydrogen gases at 77 K confirms that the microporosity is permanent. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

AB - Quick on the uptake: Following its identification during a targeted search, the intriguing crystal structure of 3,3 ,4,4 -tetra(trimethylsilylethynyl) biphenyl was investigated. Simple removal of the included solvent provides an organic crystal with an open microporous structure that has a striking similarity to that of zeolite A (see picture). Reversible adsorption of nitrogen and hydrogen gases at 77 K confirms that the microporosity is permanent. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

KW - Adsorption

KW - Microporous materials (adsorption of nitrogen and hydrogen on org. microporous crystal)

KW - adsorption nitrogen hydrogen org microporous crystal

U2 - 10.1002/anie.200900234

DO - 10.1002/anie.200900234

M3 - Article

SN - 1433-7851

VL - 48

SP - 3273

EP - 3277

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 18

ER -

Nitrogen and hydrogen adsorption by an organic microporous crystal

Abstract

Keywords

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Datasets

CCDC 713074: Experimental Crystal Structure Determination

Cite this