Nonheme ferric hydroperoxo intermediates are efficient oxidants of bromide oxidation

Anil Kumar Vardhaman; Chivukula V. Sastri; Devesh Kumar; Sam P. De Visser

doi:10.1039/c1cc13775a

Nonheme ferric hydroperoxo intermediates are efficient oxidants of bromide oxidation

Anil Kumar Vardhaman, Chivukula V. Sastri, Devesh Kumar, Sam P. De Visser

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Abstract

This work presents the first combined experimental and computational study that gives evidence of the electrophilic reactivity of a nonheme iron(iii)-hydroperoxo species. We show that in contrast to their heme counterparts the nonheme iron(iii)-hydroperoxo complexes are catalytically much more active and even more so than nonheme iron(iv)-oxo species. © 2011 The Royal Society of Chemistry.

Original language	English
Pages (from-to)	11044-11046
Number of pages	2
Journal	Chemical Communications
Volume	47
Issue number	39
DOIs	https://doi.org/10.1039/c1cc13775a
Publication status	Published - 21 Oct 2011

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title = "Nonheme ferric hydroperoxo intermediates are efficient oxidants of bromide oxidation",

abstract = "This work presents the first combined experimental and computational study that gives evidence of the electrophilic reactivity of a nonheme iron(iii)-hydroperoxo species. We show that in contrast to their heme counterparts the nonheme iron(iii)-hydroperoxo complexes are catalytically much more active and even more so than nonheme iron(iv)-oxo species. {\textcopyright} 2011 The Royal Society of Chemistry.",

author = "Vardhaman, {Anil Kumar} and Sastri, {Chivukula V.} and Devesh Kumar and {De Visser}, {Sam P.}",

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AU - Vardhaman, Anil Kumar

AU - Sastri, Chivukula V.

AU - Kumar, Devesh

AU - De Visser, Sam P.

N1 - cited By 20

PY - 2011/10/21

Y1 - 2011/10/21

N2 - This work presents the first combined experimental and computational study that gives evidence of the electrophilic reactivity of a nonheme iron(iii)-hydroperoxo species. We show that in contrast to their heme counterparts the nonheme iron(iii)-hydroperoxo complexes are catalytically much more active and even more so than nonheme iron(iv)-oxo species. © 2011 The Royal Society of Chemistry.

AB - This work presents the first combined experimental and computational study that gives evidence of the electrophilic reactivity of a nonheme iron(iii)-hydroperoxo species. We show that in contrast to their heme counterparts the nonheme iron(iii)-hydroperoxo complexes are catalytically much more active and even more so than nonheme iron(iv)-oxo species. © 2011 The Royal Society of Chemistry.

U2 - 10.1039/c1cc13775a

DO - 10.1039/c1cc13775a

M3 - Article

SN - 1359-7345

VL - 47

SP - 11044

EP - 11046

JO - Chemical Communications

JF - Chemical Communications

IS - 39

ER -

Nonheme ferric hydroperoxo intermediates are efficient oxidants of bromide oxidation

Abstract

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