Abstract
(Chemical Equation Presented) The synthesis of novel spirobisindane-based monomers for the preparation of polymers of intrinsic microporosity (PIMs) with bulky, rigid substituents is described. Polymers derived from monomers containing spiro-linked fluorene substituents display enhanced solubility and microporosity due to additional frustration of packing in the solid state. © 2008 American Chemical Society.
Original language | English |
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Pages (from-to) | 2641-2643 |
Number of pages | 2 |
Journal | Organic Letters |
Volume | 10 |
Issue number | 13 |
DOIs | |
Publication status | Published - 2008 |
Keywords
- HYDROGEN STORAGE MATERIALS
- ABSOLUTE CONFIGURATION
- 1,1'-SPIROBIINDENE
- PIMS
- SPIROCONJUGATION
- CONDENSATION
- CATALYSIS
- CATECHOL
- ACETONE
- SQUARES
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CCDC 756767: Experimental Crystal Structure Determination
Carta, M. (Contributor), Msayib, K. J. (Contributor), Budd, P. (Contributor) & Mckeown, N. B. (Contributor), Cambridge Crystallographic Data Centre, 2009
DOI: 10.5517/cctdgvh, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cctdgvh&sid=DataCite
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