Observations on the α-fluorination of α-phenylsulfanyl esters using (difluoroiodo)toluene

Michael F Greaney; William B Motherwell

doi:10.1016/s0040-4039(00)00616-x

Observations on the α-fluorination of α-phenylsulfanyl esters using (difluoroiodo)toluene

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Abstract

α-Phenylthio esters are fluorinated in the α-position when treated with the hypervalent iodine reagent 4-MeC6H4IF2. Excess reagent can lead to α-fluoro sulfoxides, which can then undergo thermal syn elimination to produce vinyl fluorides. [on SciFinder(R)]

Original language	English
Pages (from-to)	4463-4466
Number of pages	4
Journal	Tetrahedron Letters
Volume	41
DOIs	https://doi.org/10.1016/s0040-4039(00)00616-x
Publication status	Published - 2000

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@article{8d114e3c5e3a4c38bc74c9bd0c53bdd2,

title = "Observations on the α-fluorination of α-phenylsulfanyl esters using (difluoroiodo)toluene",

abstract = "α-Phenylthio esters are fluorinated in the α-position when treated with the hypervalent iodine reagent 4-MeC6H4IF2. Excess reagent can lead to α-fluoro sulfoxides, which can then undergo thermal syn elimination to produce vinyl fluorides. [on SciFinder(R)]",

author = "Greaney, {Michael F} and Motherwell, {William B}",

note = "CAPLUS AN 2000:431333(Journal)",

year = "2000",

doi = "10.1016/s0040-4039(00)00616-x",

language = "English",

volume = "41",

pages = "4463--4466",

journal = "Tetrahedron Letters",

issn = "1873-3581",

publisher = "Elsevier BV",

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TY - JOUR

T1 - Observations on the α-fluorination of α-phenylsulfanyl esters using (difluoroiodo)toluene

AU - Greaney, Michael F

AU - Motherwell, William B

N1 - CAPLUS AN 2000:431333(Journal)

PY - 2000

Y1 - 2000

N2 - α-Phenylthio esters are fluorinated in the α-position when treated with the hypervalent iodine reagent 4-MeC6H4IF2. Excess reagent can lead to α-fluoro sulfoxides, which can then undergo thermal syn elimination to produce vinyl fluorides. [on SciFinder(R)]

AB - α-Phenylthio esters are fluorinated in the α-position when treated with the hypervalent iodine reagent 4-MeC6H4IF2. Excess reagent can lead to α-fluoro sulfoxides, which can then undergo thermal syn elimination to produce vinyl fluorides. [on SciFinder(R)]

U2 - 10.1016/s0040-4039(00)00616-x

DO - 10.1016/s0040-4039(00)00616-x

M3 - Article

SN - 1873-3581

VL - 41

SP - 4463

EP - 4466

JO - Tetrahedron Letters

JF - Tetrahedron Letters

ER -

Observations on the α-fluorination of α-phenylsulfanyl esters using (difluoroiodo)toluene

Abstract

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