Octametallic 4f-phosphonate horseshoes

Karzan H. Zangana; Eufemio Moreno Pineda; Jürgen Schnack; Richard E P Winpenny

doi:10.1039/c3dt52086b

Octametallic 4f-phosphonate horseshoes

Karzan H. Zangana
, Eufemio Moreno Pineda
, Jürgen Schnack
, Richard E P Winpenny

Research output: Contribution to journal › Article › peer-review

Abstract

Three octanuclear phosphonate clusters, formulated as [Ln 8(O3PtBu)6(μ3-OH) 2(H2O)2(HOiBu)(O2C tBu)12](NH3iPr)2 (Ln = Gd, Dy and Tb), were synthesised by refluxing a mixture of pivalic acid (HO 2CtBu), Ln(NO3)3·6H 2O, tert-Butyl phosphonic acid (H2O3P tBu) and isopropylamine (iPrNH2) in isobutyl alcohol iBuOH. © 2013 The Royal Society of Chemistry.

Original language	English
Pages (from-to)	14045-14048
Number of pages	3
Journal	Dalton Transactions
Volume	42
Issue number	39
DOIs	https://doi.org/10.1039/c3dt52086b
Publication status	Published - 21 Oct 2013

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10.1039/c3dt52086b

CCDC 953479: Experimental Crystal Structure Determination
Zangana, K. H. (Contributor), Moreno Pineda, E. (Contributor), Schnack, J. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2013
DOI: 10.5517/cc1105dm, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc1105dm&sid=DataCite
Dataset
CCDC 953480: Experimental Crystal Structure Determination
Zangana, K. H. (Contributor), Moreno Pineda, E. (Contributor), Schnack, J. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2013
DOI: 10.5517/cc1105fn, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc1105fn&sid=DataCite
Dataset
CCDC 953481: Experimental Crystal Structure Determination
Zangana, K. H. (Contributor), Moreno Pineda, E. (Contributor), Schnack, J. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2013
DOI: 10.5517/cc1105gp, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc1105gp&sid=DataCite
Dataset

Cite this

@article{7022e2ce90264413b1253362d8133126,

title = "Octametallic 4f-phosphonate horseshoes",

abstract = "Three octanuclear phosphonate clusters, formulated as [Ln 8(O3PtBu)6(μ3-OH) 2(H2O)2(HOiBu)(O2C tBu)12](NH3iPr)2 (Ln = Gd, Dy and Tb), were synthesised by refluxing a mixture of pivalic acid (HO 2CtBu), Ln(NO3)3·6H 2O, tert-Butyl phosphonic acid (H2O3P tBu) and isopropylamine (iPrNH2) in isobutyl alcohol iBuOH. {\textcopyright} 2013 The Royal Society of Chemistry.",

author = "Zangana, \{Karzan H.\} and Pineda, \{Eufemio Moreno\} and J{\"u}rgen Schnack and Winpenny, \{Richard E P\}",

year = "2013",

month = oct,

day = "21",

doi = "10.1039/c3dt52086b",

language = "English",

volume = "42",

pages = "14045--14048",

journal = "Dalton Transactions",

issn = "1477-9234",

publisher = "Royal Society of Chemistry",

number = "39",

}

TY - JOUR

T1 - Octametallic 4f-phosphonate horseshoes

AU - Zangana, Karzan H.

AU - Pineda, Eufemio Moreno

AU - Schnack, Jürgen

AU - Winpenny, Richard E P

PY - 2013/10/21

Y1 - 2013/10/21

N2 - Three octanuclear phosphonate clusters, formulated as [Ln 8(O3PtBu)6(μ3-OH) 2(H2O)2(HOiBu)(O2C tBu)12](NH3iPr)2 (Ln = Gd, Dy and Tb), were synthesised by refluxing a mixture of pivalic acid (HO 2CtBu), Ln(NO3)3·6H 2O, tert-Butyl phosphonic acid (H2O3P tBu) and isopropylamine (iPrNH2) in isobutyl alcohol iBuOH. © 2013 The Royal Society of Chemistry.

AB - Three octanuclear phosphonate clusters, formulated as [Ln 8(O3PtBu)6(μ3-OH) 2(H2O)2(HOiBu)(O2C tBu)12](NH3iPr)2 (Ln = Gd, Dy and Tb), were synthesised by refluxing a mixture of pivalic acid (HO 2CtBu), Ln(NO3)3·6H 2O, tert-Butyl phosphonic acid (H2O3P tBu) and isopropylamine (iPrNH2) in isobutyl alcohol iBuOH. © 2013 The Royal Society of Chemistry.

U2 - 10.1039/c3dt52086b

DO - 10.1039/c3dt52086b

M3 - Article

SN - 1477-9234

VL - 42

SP - 14045

EP - 14048

JO - Dalton Transactions

JF - Dalton Transactions

IS - 39

ER -

Octametallic 4f-phosphonate horseshoes

Abstract

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Datasets

CCDC 953479: Experimental Crystal Structure Determination

CCDC 953480: Experimental Crystal Structure Determination

CCDC 953481: Experimental Crystal Structure Determination

Cite this