On the relationship between structure and reaction rate in olefin ring-closing metathesis

Ian W. Ashworth; Davide Carboni; Ian H. Hillier; David J. Nelson; Jonathan M. Percy; Giuseppe Rinaudo; Mark A. Vincent

doi:10.1039/c0cc02440f

On the relationship between structure and reaction rate in olefin ring-closing metathesis

Ian W. Ashworth
, Davide Carboni
, Ian H. Hillier
, David J. Nelson
, Jonathan M. Percy
, Giuseppe Rinaudo
, Mark A. Vincent

Research output: Contribution to journal › Article › peer-review

Abstract

In the RCM reactions of a series of simple α,ω-dienes, the relative order of reactivity has been unambiguously determined showing that cyclohexene forms faster than cyclopentene or cycloheptene. 1,5-Hexadiene inhibits the RCM of 1,7-octadiene; 1,5-hexadiene cannot progress to the RCM product (cyclobutene) but forms an unexpectedly stable cyclic η2-complex. © 2010 The Royal Society of Chemistry.

Original language	English
Pages (from-to)	7145-7147
Number of pages	2
Journal	Chemical Communications
Volume	46
Issue number	38
DOIs	https://doi.org/10.1039/c0cc02440f
Publication status	Published - 14 Oct 2010

Keywords

catalysts

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10.1039/c0cc02440f

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title = "On the relationship between structure and reaction rate in olefin ring-closing metathesis",

abstract = "In the RCM reactions of a series of simple α,ω-dienes, the relative order of reactivity has been unambiguously determined showing that cyclohexene forms faster than cyclopentene or cycloheptene. 1,5-Hexadiene inhibits the RCM of 1,7-octadiene; 1,5-hexadiene cannot progress to the RCM product (cyclobutene) but forms an unexpectedly stable cyclic η2-complex. {\textcopyright} 2010 The Royal Society of Chemistry.",

keywords = "catalysts",

author = "Ashworth, \{Ian W.\} and Davide Carboni and Hillier, \{Ian H.\} and Nelson, \{David J.\} and Percy, \{Jonathan M.\} and Giuseppe Rinaudo and Vincent, \{Mark A.\}",

note = "652KI Times Cited:0 Cited References Count:16",

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journal = "Chemical Communications",

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T1 - On the relationship between structure and reaction rate in olefin ring-closing metathesis

AU - Ashworth, Ian W.

AU - Carboni, Davide

AU - Hillier, Ian H.

AU - Nelson, David J.

AU - Percy, Jonathan M.

AU - Rinaudo, Giuseppe

AU - Vincent, Mark A.

N1 - 652KI Times Cited:0 Cited References Count:16

PY - 2010/10/14

Y1 - 2010/10/14

N2 - In the RCM reactions of a series of simple α,ω-dienes, the relative order of reactivity has been unambiguously determined showing that cyclohexene forms faster than cyclopentene or cycloheptene. 1,5-Hexadiene inhibits the RCM of 1,7-octadiene; 1,5-hexadiene cannot progress to the RCM product (cyclobutene) but forms an unexpectedly stable cyclic η2-complex. © 2010 The Royal Society of Chemistry.

AB - In the RCM reactions of a series of simple α,ω-dienes, the relative order of reactivity has been unambiguously determined showing that cyclohexene forms faster than cyclopentene or cycloheptene. 1,5-Hexadiene inhibits the RCM of 1,7-octadiene; 1,5-hexadiene cannot progress to the RCM product (cyclobutene) but forms an unexpectedly stable cyclic η2-complex. © 2010 The Royal Society of Chemistry.

KW - catalysts

U2 - 10.1039/c0cc02440f

DO - 10.1039/c0cc02440f

M3 - Article

SN - 1359-7345

VL - 46

SP - 7145

EP - 7147

JO - Chemical Communications

JF - Chemical Communications

IS - 38

ER -

On the relationship between structure and reaction rate in olefin ring-closing metathesis

Abstract

Keywords

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